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1-Butylquinine tetrafluoroborate
In the title salt (2S,4S,8R)-1-butyl-2-[(R)-(hydroxy)(6-methoxyquinolin-4-yl)methyl]-8-vinylquinuclidin-1-ium tetrafluoroborate, C(24)H(33)N(2)O(2) (+)·BF(4) (−), the butyl substituent at the 1-position is in an equatorial conformation with respect to the unsubstituted six-membered ring and th...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979949/ https://www.ncbi.nlm.nih.gov/pubmed/21579717 http://dx.doi.org/10.1107/S1600536809054907 |
Sumario: | In the title salt (2S,4S,8R)-1-butyl-2-[(R)-(hydroxy)(6-methoxyquinolin-4-yl)methyl]-8-vinylquinuclidin-1-ium tetrafluoroborate, C(24)H(33)N(2)O(2) (+)·BF(4) (−), the butyl substituent at the 1-position is in an equatorial conformation with respect to the unsubstituted six-membered ring and the four butyl C atoms are almost coplanar with the ring N and vinyl C atoms (r.m.s. deviation = 0.046 Å). In the crystal, the cations are linked by O—H⋯N hydrogen bonds. The F atoms of the tetrafluoroborate group are disordered over two sets of site with an occupancy raitio of 0.552 (8):0.448 (8). |
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