1-Butyl­quinine tetra­fluoro­borate

In the title salt (2S,4S,8R)-1-butyl-2-[(R)-(hydr­oxy)(6-methoxy­quinolin-4-yl)meth­yl]-8-vinyl­quinuclidin-1-ium tetra­fluoro­borate, C(24)H(33)N(2)O(2) (+)·BF(4) (−), the butyl substituent at the 1-position is in an equatorial conformation with respect to the unsubstituted six-membered ring and th...

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Detalles Bibliográficos
Autores principales: Eltaief, Sana, Retailleau, Pascal, Straver, Leo, Ben Hassine, Béchir
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979949/
https://www.ncbi.nlm.nih.gov/pubmed/21579717
http://dx.doi.org/10.1107/S1600536809054907
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author Eltaief, Sana
Retailleau, Pascal
Straver, Leo
Ben Hassine, Béchir
author_facet Eltaief, Sana
Retailleau, Pascal
Straver, Leo
Ben Hassine, Béchir
author_sort Eltaief, Sana
collection PubMed
description In the title salt (2S,4S,8R)-1-butyl-2-[(R)-(hydr­oxy)(6-methoxy­quinolin-4-yl)meth­yl]-8-vinyl­quinuclidin-1-ium tetra­fluoro­borate, C(24)H(33)N(2)O(2) (+)·BF(4) (−), the butyl substituent at the 1-position is in an equatorial conformation with respect to the unsubstituted six-membered ring and the four butyl C atoms are almost coplanar with the ring N and vinyl C atoms (r.m.s. deviation = 0.046 Å). In the crystal, the cations are linked by O—H⋯N hydrogen bonds. The F atoms of the tetra­fluoro­borate group are disordered over two sets of site with an occupancy raitio of 0.552 (8):0.448 (8).
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spelling pubmed-29799492010-12-30 1-Butyl­quinine tetra­fluoro­borate Eltaief, Sana Retailleau, Pascal Straver, Leo Ben Hassine, Béchir Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt (2S,4S,8R)-1-butyl-2-[(R)-(hydr­oxy)(6-methoxy­quinolin-4-yl)meth­yl]-8-vinyl­quinuclidin-1-ium tetra­fluoro­borate, C(24)H(33)N(2)O(2) (+)·BF(4) (−), the butyl substituent at the 1-position is in an equatorial conformation with respect to the unsubstituted six-membered ring and the four butyl C atoms are almost coplanar with the ring N and vinyl C atoms (r.m.s. deviation = 0.046 Å). In the crystal, the cations are linked by O—H⋯N hydrogen bonds. The F atoms of the tetra­fluoro­borate group are disordered over two sets of site with an occupancy raitio of 0.552 (8):0.448 (8). International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979949/ /pubmed/21579717 http://dx.doi.org/10.1107/S1600536809054907 Text en © Eltaief et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Eltaief, Sana
Retailleau, Pascal
Straver, Leo
Ben Hassine, Béchir
1-Butyl­quinine tetra­fluoro­borate
title 1-Butyl­quinine tetra­fluoro­borate
title_full 1-Butyl­quinine tetra­fluoro­borate
title_fullStr 1-Butyl­quinine tetra­fluoro­borate
title_full_unstemmed 1-Butyl­quinine tetra­fluoro­borate
title_short 1-Butyl­quinine tetra­fluoro­borate
title_sort 1-butyl­quinine tetra­fluoro­borate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979949/
https://www.ncbi.nlm.nih.gov/pubmed/21579717
http://dx.doi.org/10.1107/S1600536809054907
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