Cargando…
Bis(pyridine-κN){N (2),N (2′)-[1,1′-(pyridine-2,6-diyl)diethylidyne]benzenesulfonohydrazonato-κ(5) O,N,N′,N′′,O′}nickel(II)
In the crystal structure of the title compound, [Ni(C(21)H(19)N(5)O(4)S(2))(C(5)H(5)N)(2)], the metal center is seven-coordinate, with an approximate pentagonal-bipyramidal configuration. The Ni atom is chelated by a dianionic pentadentate Schiff base via the pyridine N atom, the two azomethine N...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979951/ https://www.ncbi.nlm.nih.gov/pubmed/21579613 http://dx.doi.org/10.1107/S1600536809055639 |
Sumario: | In the crystal structure of the title compound, [Ni(C(21)H(19)N(5)O(4)S(2))(C(5)H(5)N)(2)], the metal center is seven-coordinate, with an approximate pentagonal-bipyramidal configuration. The Ni atom is chelated by a dianionic pentadentate Schiff base via the pyridine N atom, the two azomethine N atoms and the two sulfonyl O atoms. The latter coordinate to Ni at different distances, viz. 2.3337 (12) and 2.7988 (12) Å. Two apically coordinated pyridine molecules complete the seven-coordinate geometry. The dihedral angle between the two pyridine ring planes is 68.25 (6)°. |
---|