Tris(propionitrile-κN)[1,4,7-tris­(cyano­meth­yl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]copper(II) bis­(perchlorate) dihydrate

In the title compound, [Cu(C(3)H(5)N)(3)(C(12)H(18)N(6))](ClO(4))(2)·2H(2)O, the Cu(II) atom lies on a threefold rotation axis and is coordinated in a distorted N(6) octa­hedral environment by three tertiary amines from the tridentate chelating aza­macrocyclic ligand and three propionitrile mol­ecul...

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Detalles Bibliográficos
Autores principales: Zhang, Zhong, Lu, Jianqi, Wu, Difeng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979962/
https://www.ncbi.nlm.nih.gov/pubmed/21579689
http://dx.doi.org/10.1107/S1600536810003211
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author Zhang, Zhong
Lu, Jianqi
Wu, Difeng
author_facet Zhang, Zhong
Lu, Jianqi
Wu, Difeng
author_sort Zhang, Zhong
collection PubMed
description In the title compound, [Cu(C(3)H(5)N)(3)(C(12)H(18)N(6))](ClO(4))(2)·2H(2)O, the Cu(II) atom lies on a threefold rotation axis and is coordinated in a distorted N(6) octa­hedral environment by three tertiary amines from the tridentate chelating aza­macrocyclic ligand and three propionitrile mol­ecules. Inter­molecular non-classical C—H⋯N hydrogen bonding inter­links the [Cu(C(3)H(5)N)(3)(C(12)H(18)N(6))](2+) cations into a two-dimensional supra­molecular sheet extending along the ab plane. The crystal packing also exhibits weak C—H⋯O inter­actions.
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spelling pubmed-29799622010-12-30 Tris(propionitrile-κN)[1,4,7-tris­(cyano­meth­yl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]copper(II) bis­(perchlorate) dihydrate Zhang, Zhong Lu, Jianqi Wu, Difeng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(3)H(5)N)(3)(C(12)H(18)N(6))](ClO(4))(2)·2H(2)O, the Cu(II) atom lies on a threefold rotation axis and is coordinated in a distorted N(6) octa­hedral environment by three tertiary amines from the tridentate chelating aza­macrocyclic ligand and three propionitrile mol­ecules. Inter­molecular non-classical C—H⋯N hydrogen bonding inter­links the [Cu(C(3)H(5)N)(3)(C(12)H(18)N(6))](2+) cations into a two-dimensional supra­molecular sheet extending along the ab plane. The crystal packing also exhibits weak C—H⋯O inter­actions. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979962/ /pubmed/21579689 http://dx.doi.org/10.1107/S1600536810003211 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Zhong
Lu, Jianqi
Wu, Difeng
Tris(propionitrile-κN)[1,4,7-tris­(cyano­meth­yl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]copper(II) bis­(perchlorate) dihydrate
title Tris(propionitrile-κN)[1,4,7-tris­(cyano­meth­yl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]copper(II) bis­(perchlorate) dihydrate
title_full Tris(propionitrile-κN)[1,4,7-tris­(cyano­meth­yl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]copper(II) bis­(perchlorate) dihydrate
title_fullStr Tris(propionitrile-κN)[1,4,7-tris­(cyano­meth­yl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]copper(II) bis­(perchlorate) dihydrate
title_full_unstemmed Tris(propionitrile-κN)[1,4,7-tris­(cyano­meth­yl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]copper(II) bis­(perchlorate) dihydrate
title_short Tris(propionitrile-κN)[1,4,7-tris­(cyano­meth­yl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]copper(II) bis­(perchlorate) dihydrate
title_sort tris(propionitrile-κn)[1,4,7-tris­(cyano­meth­yl)-1,4,7-triaza­cyclo­nonane-κ(3) n (1),n (4),n (7)]copper(ii) bis­(perchlorate) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979962/
https://www.ncbi.nlm.nih.gov/pubmed/21579689
http://dx.doi.org/10.1107/S1600536810003211
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AT wudifeng trispropionitrilekn147triscyanomethyl147triazacyclononanek3n1n4n7copperiibisperchloratedihydrate

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