{2-[2-(Ethyl­amino)ethyl­imino­meth­yl]-5-methoxy­phenolato}thio­cyanato­nickel(II)

In the title mononuclear nickel(II) complex, [Ni(C(12)H(17)N(2)O(2))(NCS)], the metal atom is four-coordinated in a tetra­hedrally distorted square-planar geometry by the phenolate O atom, the imine N atom and the amine N atom of the Schiff base ligand and by the N atom of a thio­cyanate ligand. In...

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Detalles Bibliográficos
Autor principal: Liu, Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979965/
https://www.ncbi.nlm.nih.gov/pubmed/21579660
http://dx.doi.org/10.1107/S1600536810002357
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author Liu, Lin
author_facet Liu, Lin
author_sort Liu, Lin
collection PubMed
description In the title mononuclear nickel(II) complex, [Ni(C(12)H(17)N(2)O(2))(NCS)], the metal atom is four-coordinated in a tetra­hedrally distorted square-planar geometry by the phenolate O atom, the imine N atom and the amine N atom of the Schiff base ligand and by the N atom of a thio­cyanate ligand. In the crystal structure, centrosymmetrically related mol­ecules are linked into dimers through inter­molecular N—H⋯O hydrogen bonds. These dimers are further connected by inter­molecular C—H⋯S hydrogen bonds, forming chains running parallel to [101].
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spelling pubmed-29799652010-12-30 {2-[2-(Ethyl­amino)ethyl­imino­meth­yl]-5-methoxy­phenolato}thio­cyanato­nickel(II) Liu, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear nickel(II) complex, [Ni(C(12)H(17)N(2)O(2))(NCS)], the metal atom is four-coordinated in a tetra­hedrally distorted square-planar geometry by the phenolate O atom, the imine N atom and the amine N atom of the Schiff base ligand and by the N atom of a thio­cyanate ligand. In the crystal structure, centrosymmetrically related mol­ecules are linked into dimers through inter­molecular N—H⋯O hydrogen bonds. These dimers are further connected by inter­molecular C—H⋯S hydrogen bonds, forming chains running parallel to [101]. International Union of Crystallography 2010-01-23 /pmc/articles/PMC2979965/ /pubmed/21579660 http://dx.doi.org/10.1107/S1600536810002357 Text en © Lin Liu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Lin
{2-[2-(Ethyl­amino)ethyl­imino­meth­yl]-5-methoxy­phenolato}thio­cyanato­nickel(II)
title {2-[2-(Ethyl­amino)ethyl­imino­meth­yl]-5-methoxy­phenolato}thio­cyanato­nickel(II)
title_full {2-[2-(Ethyl­amino)ethyl­imino­meth­yl]-5-methoxy­phenolato}thio­cyanato­nickel(II)
title_fullStr {2-[2-(Ethyl­amino)ethyl­imino­meth­yl]-5-methoxy­phenolato}thio­cyanato­nickel(II)
title_full_unstemmed {2-[2-(Ethyl­amino)ethyl­imino­meth­yl]-5-methoxy­phenolato}thio­cyanato­nickel(II)
title_short {2-[2-(Ethyl­amino)ethyl­imino­meth­yl]-5-methoxy­phenolato}thio­cyanato­nickel(II)
title_sort {2-[2-(ethyl­amino)ethyl­imino­meth­yl]-5-methoxy­phenolato}thio­cyanato­nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979965/
https://www.ncbi.nlm.nih.gov/pubmed/21579660
http://dx.doi.org/10.1107/S1600536810002357
work_keys_str_mv AT liulin 22ethylaminoethyliminomethyl5methoxyphenolatothiocyanatonickelii

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