cis,trans,cis,cis-7-tert-Butyl­dimethyl­silyl­oxy-4,10-dimethyl­tetra­cyclo[5.4.1.0(4,12).0(10,12)]dodecan-2-one

In the structure of the title compound, C(20)H(34)O(2)Si, a cis,trans,cis,cis-[4.5.5.5]fenestrane derivative, the geometry of the central C(C)(4) substructure shows considerable distortion from an ideal tetra­hedral arrangement towards planarity, with two opposite bridgehead bond angles of 128.87 (1...

Descripción completa

Detalles Bibliográficos
Autores principales: Weyermann, Philipp, Keese, Reinhart, Stoeckli-Evans, Helen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979968/
https://www.ncbi.nlm.nih.gov/pubmed/21579769
http://dx.doi.org/10.1107/S1600536810000887
_version_ 1782191545488769024
author Weyermann, Philipp
Keese, Reinhart
Stoeckli-Evans, Helen
author_facet Weyermann, Philipp
Keese, Reinhart
Stoeckli-Evans, Helen
author_sort Weyermann, Philipp
collection PubMed
description In the structure of the title compound, C(20)H(34)O(2)Si, a cis,trans,cis,cis-[4.5.5.5]fenestrane derivative, the geometry of the central C(C)(4) substructure shows considerable distortion from an ideal tetra­hedral arrangement towards planarity, with two opposite bridgehead bond angles of 128.87 (18) and 122.83 (17)°. The other bridgehead angle of the trans-bicyclo­[3.3.0]octane subunit is also large [126.57 (19)°].
format Text
id pubmed-2979968
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29799682010-12-30 cis,trans,cis,cis-7-tert-Butyl­dimethyl­silyl­oxy-4,10-dimethyl­tetra­cyclo[5.4.1.0(4,12).0(10,12)]dodecan-2-one Weyermann, Philipp Keese, Reinhart Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Organic Papers In the structure of the title compound, C(20)H(34)O(2)Si, a cis,trans,cis,cis-[4.5.5.5]fenestrane derivative, the geometry of the central C(C)(4) substructure shows considerable distortion from an ideal tetra­hedral arrangement towards planarity, with two opposite bridgehead bond angles of 128.87 (18) and 122.83 (17)°. The other bridgehead angle of the trans-bicyclo­[3.3.0]octane subunit is also large [126.57 (19)°]. International Union of Crystallography 2010-01-13 /pmc/articles/PMC2979968/ /pubmed/21579769 http://dx.doi.org/10.1107/S1600536810000887 Text en © Weyermann et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Weyermann, Philipp
Keese, Reinhart
Stoeckli-Evans, Helen
cis,trans,cis,cis-7-tert-Butyl­dimethyl­silyl­oxy-4,10-dimethyl­tetra­cyclo[5.4.1.0(4,12).0(10,12)]dodecan-2-one
title cis,trans,cis,cis-7-tert-Butyl­dimethyl­silyl­oxy-4,10-dimethyl­tetra­cyclo[5.4.1.0(4,12).0(10,12)]dodecan-2-one
title_full cis,trans,cis,cis-7-tert-Butyl­dimethyl­silyl­oxy-4,10-dimethyl­tetra­cyclo[5.4.1.0(4,12).0(10,12)]dodecan-2-one
title_fullStr cis,trans,cis,cis-7-tert-Butyl­dimethyl­silyl­oxy-4,10-dimethyl­tetra­cyclo[5.4.1.0(4,12).0(10,12)]dodecan-2-one
title_full_unstemmed cis,trans,cis,cis-7-tert-Butyl­dimethyl­silyl­oxy-4,10-dimethyl­tetra­cyclo[5.4.1.0(4,12).0(10,12)]dodecan-2-one
title_short cis,trans,cis,cis-7-tert-Butyl­dimethyl­silyl­oxy-4,10-dimethyl­tetra­cyclo[5.4.1.0(4,12).0(10,12)]dodecan-2-one
title_sort cis,trans,cis,cis-7-tert-butyl­dimethyl­silyl­oxy-4,10-dimethyl­tetra­cyclo[5.4.1.0(4,12).0(10,12)]dodecan-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979968/
https://www.ncbi.nlm.nih.gov/pubmed/21579769
http://dx.doi.org/10.1107/S1600536810000887
work_keys_str_mv AT weyermannphilipp cistransciscis7tertbutyldimethylsilyloxy410dimethyltetracyclo541041201012dodecan2one
AT keesereinhart cistransciscis7tertbutyldimethylsilyloxy410dimethyltetracyclo541041201012dodecan2one
AT stoecklievanshelen cistransciscis7tertbutyldimethylsilyloxy410dimethyltetracyclo541041201012dodecan2one

Ejemplares similares