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Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) ethane-1,2-diol solvate

The title compound, [Zn(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), is a six-coordinate zinc(II) complex with a distorted octa­hedral coordination geometry. The Zn(II) atom is bonded by two O atoms of the bidentate chelating sulfate ligand and four N atoms of the two chelating 2,2′-bipyridine ligands. T...

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Detalles Bibliográficos
Autor principal: Zhong, Kai-Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979970/
https://www.ncbi.nlm.nih.gov/pubmed/21579615
http://dx.doi.org/10.1107/S1600536809055433
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author Zhong, Kai-Long
author_facet Zhong, Kai-Long
author_sort Zhong, Kai-Long
collection PubMed
description The title compound, [Zn(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), is a six-coordinate zinc(II) complex with a distorted octa­hedral coordination geometry. The Zn(II) atom is bonded by two O atoms of the bidentate chelating sulfate ligand and four N atoms of the two chelating 2,2′-bipyridine ligands. The Zn—N bond distances range from 2.1287 (17) to 2.1452 (17) Å and the Zn—O bond distance is 2.1811 (15) Å. The two chelating NCCN groups subtend a dihedral angle of 81.1 (1)°. In the crystal structure, the [ZnSO(4)(C(10)H(8)N(2))(2)] and C(2)H(6)O(2) units are connected by inter­molecular O—H⋯O hydrogen bonding, which leads to additional stabilization of the structure.
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spelling pubmed-29799702010-12-30 Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) ethane-1,2-diol solvate Zhong, Kai-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), is a six-coordinate zinc(II) complex with a distorted octa­hedral coordination geometry. The Zn(II) atom is bonded by two O atoms of the bidentate chelating sulfate ligand and four N atoms of the two chelating 2,2′-bipyridine ligands. The Zn—N bond distances range from 2.1287 (17) to 2.1452 (17) Å and the Zn—O bond distance is 2.1811 (15) Å. The two chelating NCCN groups subtend a dihedral angle of 81.1 (1)°. In the crystal structure, the [ZnSO(4)(C(10)H(8)N(2))(2)] and C(2)H(6)O(2) units are connected by inter­molecular O—H⋯O hydrogen bonding, which leads to additional stabilization of the structure. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979970/ /pubmed/21579615 http://dx.doi.org/10.1107/S1600536809055433 Text en © Kai-Long Zhong 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhong, Kai-Long
Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) ethane-1,2-diol solvate
title Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) ethane-1,2-diol solvate
title_full Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) ethane-1,2-diol solvate
title_fullStr Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) ethane-1,2-diol solvate
title_full_unstemmed Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) ethane-1,2-diol solvate
title_short Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) ethane-1,2-diol solvate
title_sort bis(2,2′-bipyridyl-κ(2) n,n′)(sulfato-κ(2) o,o′)zinc(ii) ethane-1,2-diol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979970/
https://www.ncbi.nlm.nih.gov/pubmed/21579615
http://dx.doi.org/10.1107/S1600536809055433
work_keys_str_mv AT zhongkailong bis22bipyridylk2nnsulfatok2oozinciiethane12diolsolvate