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Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) ethane-1,2-diol solvate
The title compound, [Zn(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), is a six-coordinate zinc(II) complex with a distorted octahedral coordination geometry. The Zn(II) atom is bonded by two O atoms of the bidentate chelating sulfate ligand and four N atoms of the two chelating 2,2′-bipyridine ligands. T...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979970/ https://www.ncbi.nlm.nih.gov/pubmed/21579615 http://dx.doi.org/10.1107/S1600536809055433 |
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author | Zhong, Kai-Long |
author_facet | Zhong, Kai-Long |
author_sort | Zhong, Kai-Long |
collection | PubMed |
description | The title compound, [Zn(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), is a six-coordinate zinc(II) complex with a distorted octahedral coordination geometry. The Zn(II) atom is bonded by two O atoms of the bidentate chelating sulfate ligand and four N atoms of the two chelating 2,2′-bipyridine ligands. The Zn—N bond distances range from 2.1287 (17) to 2.1452 (17) Å and the Zn—O bond distance is 2.1811 (15) Å. The two chelating NCCN groups subtend a dihedral angle of 81.1 (1)°. In the crystal structure, the [ZnSO(4)(C(10)H(8)N(2))(2)] and C(2)H(6)O(2) units are connected by intermolecular O—H⋯O hydrogen bonding, which leads to additional stabilization of the structure. |
format | Text |
id | pubmed-2979970 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29799702010-12-30 Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) ethane-1,2-diol solvate Zhong, Kai-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), is a six-coordinate zinc(II) complex with a distorted octahedral coordination geometry. The Zn(II) atom is bonded by two O atoms of the bidentate chelating sulfate ligand and four N atoms of the two chelating 2,2′-bipyridine ligands. The Zn—N bond distances range from 2.1287 (17) to 2.1452 (17) Å and the Zn—O bond distance is 2.1811 (15) Å. The two chelating NCCN groups subtend a dihedral angle of 81.1 (1)°. In the crystal structure, the [ZnSO(4)(C(10)H(8)N(2))(2)] and C(2)H(6)O(2) units are connected by intermolecular O—H⋯O hydrogen bonding, which leads to additional stabilization of the structure. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979970/ /pubmed/21579615 http://dx.doi.org/10.1107/S1600536809055433 Text en © Kai-Long Zhong 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhong, Kai-Long Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)zinc(II) ethane-1,2-diol solvate |
title | Bis(2,2′-bipyridyl-κ(2)
N,N′)(sulfato-κ(2)
O,O′)zinc(II) ethane-1,2-diol solvate |
title_full | Bis(2,2′-bipyridyl-κ(2)
N,N′)(sulfato-κ(2)
O,O′)zinc(II) ethane-1,2-diol solvate |
title_fullStr | Bis(2,2′-bipyridyl-κ(2)
N,N′)(sulfato-κ(2)
O,O′)zinc(II) ethane-1,2-diol solvate |
title_full_unstemmed | Bis(2,2′-bipyridyl-κ(2)
N,N′)(sulfato-κ(2)
O,O′)zinc(II) ethane-1,2-diol solvate |
title_short | Bis(2,2′-bipyridyl-κ(2)
N,N′)(sulfato-κ(2)
O,O′)zinc(II) ethane-1,2-diol solvate |
title_sort | bis(2,2′-bipyridyl-κ(2)
n,n′)(sulfato-κ(2)
o,o′)zinc(ii) ethane-1,2-diol solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979970/ https://www.ncbi.nlm.nih.gov/pubmed/21579615 http://dx.doi.org/10.1107/S1600536809055433 |
work_keys_str_mv | AT zhongkailong bis22bipyridylk2nnsulfatok2oozinciiethane12diolsolvate |