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trans-Bis(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)bis­(4-methyl-1,2,3-selenadiazole-κN (3))copper(II)

In the title compound, [Cu(C(5)HF(6)O(2))(2)(C(3)H(4)N(2)Se)(2)], the Cu(II) atom (site symmetry [Image: see text]) is coordinated by two O,O′-bidentate 1,1,1,5,5,5-hexa­fluoro-2,4-penta­nedione (hp) ligands and two 4-methyl-1,2,3-selenadiazole mol­ecules, resulting in a slightly distorted trans-CuN...

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Detalles Bibliográficos
Autores principales: Boag, Neil M., Jackson, Andrew D., Lickiss, Paul D., Pilkington, Richard D., Redhouse, Alan D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979973/
https://www.ncbi.nlm.nih.gov/pubmed/21579694
http://dx.doi.org/10.1107/S1600536810001297
Descripción
Sumario:In the title compound, [Cu(C(5)HF(6)O(2))(2)(C(3)H(4)N(2)Se)(2)], the Cu(II) atom (site symmetry [Image: see text]) is coordinated by two O,O′-bidentate 1,1,1,5,5,5-hexa­fluoro-2,4-penta­nedione (hp) ligands and two 4-methyl-1,2,3-selenadiazole mol­ecules, resulting in a slightly distorted trans-CuN(2)O(4) octa­hedral geometry in which the cis angles deviate by less than 3° from 90°. The selenadiazole plane is canted at 73.13 (17)° to the square plane defined by the penta­nedionate O atoms. The F atoms of one of the hp ligands are disordered over two sets of sites in a 0.66 (3):0.34 (3) ratio. There are no significant inter­molecular inter­actions in the crystal.