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trans-Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2) O,O′)bis(4-methyl-1,2,3-selenadiazole-κN (3))copper(II)
In the title compound, [Cu(C(5)HF(6)O(2))(2)(C(3)H(4)N(2)Se)(2)], the Cu(II) atom (site symmetry [Image: see text]) is coordinated by two O,O′-bidentate 1,1,1,5,5,5-hexafluoro-2,4-pentanedione (hp) ligands and two 4-methyl-1,2,3-selenadiazole molecules, resulting in a slightly distorted trans-CuN...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979973/ https://www.ncbi.nlm.nih.gov/pubmed/21579694 http://dx.doi.org/10.1107/S1600536810001297 |
| _version_ | 1782191546686242816 |
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| author | Boag, Neil M. Jackson, Andrew D. Lickiss, Paul D. Pilkington, Richard D. Redhouse, Alan D. |
| author_facet | Boag, Neil M. Jackson, Andrew D. Lickiss, Paul D. Pilkington, Richard D. Redhouse, Alan D. |
| author_sort | Boag, Neil M. |
| collection | PubMed |
| description | In the title compound, [Cu(C(5)HF(6)O(2))(2)(C(3)H(4)N(2)Se)(2)], the Cu(II) atom (site symmetry [Image: see text]) is coordinated by two O,O′-bidentate 1,1,1,5,5,5-hexafluoro-2,4-pentanedione (hp) ligands and two 4-methyl-1,2,3-selenadiazole molecules, resulting in a slightly distorted trans-CuN(2)O(4) octahedral geometry in which the cis angles deviate by less than 3° from 90°. The selenadiazole plane is canted at 73.13 (17)° to the square plane defined by the pentanedionate O atoms. The F atoms of one of the hp ligands are disordered over two sets of sites in a 0.66 (3):0.34 (3) ratio. There are no significant intermolecular interactions in the crystal. |
| format | Text |
| id | pubmed-2979973 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29799732010-12-30 trans-Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2) O,O′)bis(4-methyl-1,2,3-selenadiazole-κN (3))copper(II) Boag, Neil M. Jackson, Andrew D. Lickiss, Paul D. Pilkington, Richard D. Redhouse, Alan D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(5)HF(6)O(2))(2)(C(3)H(4)N(2)Se)(2)], the Cu(II) atom (site symmetry [Image: see text]) is coordinated by two O,O′-bidentate 1,1,1,5,5,5-hexafluoro-2,4-pentanedione (hp) ligands and two 4-methyl-1,2,3-selenadiazole molecules, resulting in a slightly distorted trans-CuN(2)O(4) octahedral geometry in which the cis angles deviate by less than 3° from 90°. The selenadiazole plane is canted at 73.13 (17)° to the square plane defined by the pentanedionate O atoms. The F atoms of one of the hp ligands are disordered over two sets of sites in a 0.66 (3):0.34 (3) ratio. There are no significant intermolecular interactions in the crystal. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979973/ /pubmed/21579694 http://dx.doi.org/10.1107/S1600536810001297 Text en © Boag et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Boag, Neil M. Jackson, Andrew D. Lickiss, Paul D. Pilkington, Richard D. Redhouse, Alan D. trans-Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2) O,O′)bis(4-methyl-1,2,3-selenadiazole-κN (3))copper(II) |
| title |
trans-Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2)
O,O′)bis(4-methyl-1,2,3-selenadiazole-κN
(3))copper(II) |
| title_full |
trans-Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2)
O,O′)bis(4-methyl-1,2,3-selenadiazole-κN
(3))copper(II) |
| title_fullStr |
trans-Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2)
O,O′)bis(4-methyl-1,2,3-selenadiazole-κN
(3))copper(II) |
| title_full_unstemmed |
trans-Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2)
O,O′)bis(4-methyl-1,2,3-selenadiazole-κN
(3))copper(II) |
| title_short |
trans-Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2)
O,O′)bis(4-methyl-1,2,3-selenadiazole-κN
(3))copper(II) |
| title_sort | trans-bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2)
o,o′)bis(4-methyl-1,2,3-selenadiazole-κn
(3))copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979973/ https://www.ncbi.nlm.nih.gov/pubmed/21579694 http://dx.doi.org/10.1107/S1600536810001297 |
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