cis-Aqua­bis(2,2′-bipyridine-κ(2) N,N′)fluoridochromium(III) bis­(perchlorate) dihydrate

The title mixed aqua–fluoride complex, [CrF(C(10)H(8)N(2))(2)(H(2)O)](ClO(4))(2)·2H(2)O, has been synthesized by aqua­tion of the corresponding difluoride complex using lanthan­ide(III) ions as F(−) acceptors. The complex crystallizes with a Cr(III) ion at the center of a distorted octa­hedral coord...

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Detalles Bibliográficos
Autores principales: Birk, Torben, Bendix, Jesper
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979974/
https://www.ncbi.nlm.nih.gov/pubmed/21579608
http://dx.doi.org/10.1107/S1600536810000127
Descripción
Sumario:The title mixed aqua–fluoride complex, [CrF(C(10)H(8)N(2))(2)(H(2)O)](ClO(4))(2)·2H(2)O, has been synthesized by aqua­tion of the corresponding difluoride complex using lanthan­ide(III) ions as F(−) acceptors. The complex crystallizes with a Cr(III) ion at the center of a distorted octa­hedral coordination polyhedron with a cis arrangement of ligands. The crystal packing shows a hydrogen-bonding pattern involving water mol­ecules, the coordinated F atom and the perchlorate anions

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