cis-Aqua­bis(2,2′-bipyridine-κ(2) N,N′)fluoridochromium(III) bis­(perchlorate) dihydrate

The title mixed aqua–fluoride complex, [CrF(C(10)H(8)N(2))(2)(H(2)O)](ClO(4))(2)·2H(2)O, has been synthesized by aqua­tion of the corresponding difluoride complex using lanthan­ide(III) ions as F(−) acceptors. The complex crystallizes with a Cr(III) ion at the center of a distorted octa­hedral coord...

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Detalles Bibliográficos
Autores principales: Birk, Torben, Bendix, Jesper
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979974/
https://www.ncbi.nlm.nih.gov/pubmed/21579608
http://dx.doi.org/10.1107/S1600536810000127
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author Birk, Torben
Bendix, Jesper
author_facet Birk, Torben
Bendix, Jesper
author_sort Birk, Torben
collection PubMed
description The title mixed aqua–fluoride complex, [CrF(C(10)H(8)N(2))(2)(H(2)O)](ClO(4))(2)·2H(2)O, has been synthesized by aqua­tion of the corresponding difluoride complex using lanthan­ide(III) ions as F(−) acceptors. The complex crystallizes with a Cr(III) ion at the center of a distorted octa­hedral coordination polyhedron with a cis arrangement of ligands. The crystal packing shows a hydrogen-bonding pattern involving water mol­ecules, the coordinated F atom and the perchlorate anions
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spelling pubmed-29799742010-12-30 cis-Aqua­bis(2,2′-bipyridine-κ(2) N,N′)fluoridochromium(III) bis­(perchlorate) dihydrate Birk, Torben Bendix, Jesper Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mixed aqua–fluoride complex, [CrF(C(10)H(8)N(2))(2)(H(2)O)](ClO(4))(2)·2H(2)O, has been synthesized by aqua­tion of the corresponding difluoride complex using lanthan­ide(III) ions as F(−) acceptors. The complex crystallizes with a Cr(III) ion at the center of a distorted octa­hedral coordination polyhedron with a cis arrangement of ligands. The crystal packing shows a hydrogen-bonding pattern involving water mol­ecules, the coordinated F atom and the perchlorate anions International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979974/ /pubmed/21579608 http://dx.doi.org/10.1107/S1600536810000127 Text en © Birk and Bendix 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Birk, Torben
Bendix, Jesper
cis-Aqua­bis(2,2′-bipyridine-κ(2) N,N′)fluoridochromium(III) bis­(perchlorate) dihydrate
title cis-Aqua­bis(2,2′-bipyridine-κ(2) N,N′)fluoridochromium(III) bis­(perchlorate) dihydrate
title_full cis-Aqua­bis(2,2′-bipyridine-κ(2) N,N′)fluoridochromium(III) bis­(perchlorate) dihydrate
title_fullStr cis-Aqua­bis(2,2′-bipyridine-κ(2) N,N′)fluoridochromium(III) bis­(perchlorate) dihydrate
title_full_unstemmed cis-Aqua­bis(2,2′-bipyridine-κ(2) N,N′)fluoridochromium(III) bis­(perchlorate) dihydrate
title_short cis-Aqua­bis(2,2′-bipyridine-κ(2) N,N′)fluoridochromium(III) bis­(perchlorate) dihydrate
title_sort cis-aqua­bis(2,2′-bipyridine-κ(2) n,n′)fluoridochromium(iii) bis­(perchlorate) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979974/
https://www.ncbi.nlm.nih.gov/pubmed/21579608
http://dx.doi.org/10.1107/S1600536810000127
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