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catena-Poly[[aqua(4-ethylbenzoic acid-κO)lanthanum(III)]-tri-μ-4-ethylbenzoato]
The reaction of lanthanum nitrate and 4-ethylbenzoic acid (EBAH) in aqueous solution yielded the title polymer, [La(C(9)H(9)O(2))(3)(C(9)H(10)O(2))(H(2)O)](n). The asymmetric unit contains one La(III) atom, three 4-ethylbenzoate (EBA) ligands, one neutral EBAH ligand and one coordinated water mol...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979983/ https://www.ncbi.nlm.nih.gov/pubmed/21579652 http://dx.doi.org/10.1107/S160053681000190X |
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author | Yang, Juan Li, Jiantong Wang, Qiufen |
author_facet | Yang, Juan Li, Jiantong Wang, Qiufen |
author_sort | Yang, Juan |
collection | PubMed |
description | The reaction of lanthanum nitrate and 4-ethylbenzoic acid (EBAH) in aqueous solution yielded the title polymer, [La(C(9)H(9)O(2))(3)(C(9)H(10)O(2))(H(2)O)](n). The asymmetric unit contains one La(III) atom, three 4-ethylbenzoate (EBA) ligands, one neutral EBAH ligand and one coordinated water molecule. Each La(III) ion is eight-coordinated by six O atoms from six bridging-bidentate EBA ligands, one O atom from a monodentate EBAH ligand and one water O atom in a distorted bicapped trigonal-prismatic geometry. The adjacent La(III) ions are linked by the carboxylate groups of EBA ligands in a bridging-bidetate coordination mode, resulting in an infinite chain structure along the c axis. O—H⋯O hydrogen-bonding interactions involving the water molecules, carboxylate groups and carboxyl H atoms are formed within the one-dimensional polymer. One of the ethyl groups is disordered over two positions with occupancies of 0.717 (7) and 0.283 (7). |
format | Text |
id | pubmed-2979983 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29799832010-12-30 catena-Poly[[aqua(4-ethylbenzoic acid-κO)lanthanum(III)]-tri-μ-4-ethylbenzoato] Yang, Juan Li, Jiantong Wang, Qiufen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of lanthanum nitrate and 4-ethylbenzoic acid (EBAH) in aqueous solution yielded the title polymer, [La(C(9)H(9)O(2))(3)(C(9)H(10)O(2))(H(2)O)](n). The asymmetric unit contains one La(III) atom, three 4-ethylbenzoate (EBA) ligands, one neutral EBAH ligand and one coordinated water molecule. Each La(III) ion is eight-coordinated by six O atoms from six bridging-bidentate EBA ligands, one O atom from a monodentate EBAH ligand and one water O atom in a distorted bicapped trigonal-prismatic geometry. The adjacent La(III) ions are linked by the carboxylate groups of EBA ligands in a bridging-bidetate coordination mode, resulting in an infinite chain structure along the c axis. O—H⋯O hydrogen-bonding interactions involving the water molecules, carboxylate groups and carboxyl H atoms are formed within the one-dimensional polymer. One of the ethyl groups is disordered over two positions with occupancies of 0.717 (7) and 0.283 (7). International Union of Crystallography 2010-01-20 /pmc/articles/PMC2979983/ /pubmed/21579652 http://dx.doi.org/10.1107/S160053681000190X Text en © Yang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Juan Li, Jiantong Wang, Qiufen catena-Poly[[aqua(4-ethylbenzoic acid-κO)lanthanum(III)]-tri-μ-4-ethylbenzoato] |
title |
catena-Poly[[aqua(4-ethylbenzoic acid-κO)lanthanum(III)]-tri-μ-4-ethylbenzoato] |
title_full |
catena-Poly[[aqua(4-ethylbenzoic acid-κO)lanthanum(III)]-tri-μ-4-ethylbenzoato] |
title_fullStr |
catena-Poly[[aqua(4-ethylbenzoic acid-κO)lanthanum(III)]-tri-μ-4-ethylbenzoato] |
title_full_unstemmed |
catena-Poly[[aqua(4-ethylbenzoic acid-κO)lanthanum(III)]-tri-μ-4-ethylbenzoato] |
title_short |
catena-Poly[[aqua(4-ethylbenzoic acid-κO)lanthanum(III)]-tri-μ-4-ethylbenzoato] |
title_sort | catena-poly[[aqua(4-ethylbenzoic acid-κo)lanthanum(iii)]-tri-μ-4-ethylbenzoato] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979983/ https://www.ncbi.nlm.nih.gov/pubmed/21579652 http://dx.doi.org/10.1107/S160053681000190X |
work_keys_str_mv | AT yangjuan catenapolyaqua4ethylbenzoicacidkolanthanumiiitrim4ethylbenzoato AT lijiantong catenapolyaqua4ethylbenzoicacidkolanthanumiiitrim4ethylbenzoato AT wangqiufen catenapolyaqua4ethylbenzoicacidkolanthanumiiitrim4ethylbenzoato |