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catena-Poly[[aqua­(4-ethyl­benzoic acid-κO)lanthanum(III)]-tri-μ-4-ethyl­benzoato]

The reaction of lanthanum nitrate and 4-ethyl­benzoic acid (EBAH) in aqueous solution yielded the title polymer, [La(C(9)H(9)O(2))(3)(C(9)H(10)O(2))(H(2)O)](n). The asymmetric unit contains one La(III) atom, three 4-ethyl­benzoate (EBA) ligands, one neutral EBAH ligand and one coordinated water mol­...

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Detalles Bibliográficos
Autores principales: Yang, Juan, Li, Jiantong, Wang, Qiufen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979983/
https://www.ncbi.nlm.nih.gov/pubmed/21579652
http://dx.doi.org/10.1107/S160053681000190X
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author Yang, Juan
Li, Jiantong
Wang, Qiufen
author_facet Yang, Juan
Li, Jiantong
Wang, Qiufen
author_sort Yang, Juan
collection PubMed
description The reaction of lanthanum nitrate and 4-ethyl­benzoic acid (EBAH) in aqueous solution yielded the title polymer, [La(C(9)H(9)O(2))(3)(C(9)H(10)O(2))(H(2)O)](n). The asymmetric unit contains one La(III) atom, three 4-ethyl­benzoate (EBA) ligands, one neutral EBAH ligand and one coordinated water mol­ecule. Each La(III) ion is eight-coordinated by six O atoms from six bridging-bidentate EBA ligands, one O atom from a monodentate EBAH ligand and one water O atom in a distorted bicapped trigonal-prismatic geometry. The adjacent La(III) ions are linked by the carboxyl­ate groups of EBA ligands in a bridging-bidetate coordination mode, resulting in an infinite chain structure along the c axis. O—H⋯O hydrogen-bonding inter­actions involving the water mol­ecules, carboxyl­ate groups and carboxyl H atoms are formed within the one-dimensional polymer. One of the ethyl groups is disordered over two positions with occupancies of 0.717 (7) and 0.283 (7).
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spelling pubmed-29799832010-12-30 catena-Poly[[aqua­(4-ethyl­benzoic acid-κO)lanthanum(III)]-tri-μ-4-ethyl­benzoato] Yang, Juan Li, Jiantong Wang, Qiufen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of lanthanum nitrate and 4-ethyl­benzoic acid (EBAH) in aqueous solution yielded the title polymer, [La(C(9)H(9)O(2))(3)(C(9)H(10)O(2))(H(2)O)](n). The asymmetric unit contains one La(III) atom, three 4-ethyl­benzoate (EBA) ligands, one neutral EBAH ligand and one coordinated water mol­ecule. Each La(III) ion is eight-coordinated by six O atoms from six bridging-bidentate EBA ligands, one O atom from a monodentate EBAH ligand and one water O atom in a distorted bicapped trigonal-prismatic geometry. The adjacent La(III) ions are linked by the carboxyl­ate groups of EBA ligands in a bridging-bidetate coordination mode, resulting in an infinite chain structure along the c axis. O—H⋯O hydrogen-bonding inter­actions involving the water mol­ecules, carboxyl­ate groups and carboxyl H atoms are formed within the one-dimensional polymer. One of the ethyl groups is disordered over two positions with occupancies of 0.717 (7) and 0.283 (7). International Union of Crystallography 2010-01-20 /pmc/articles/PMC2979983/ /pubmed/21579652 http://dx.doi.org/10.1107/S160053681000190X Text en © Yang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Juan
Li, Jiantong
Wang, Qiufen
catena-Poly[[aqua­(4-ethyl­benzoic acid-κO)lanthanum(III)]-tri-μ-4-ethyl­benzoato]
title catena-Poly[[aqua­(4-ethyl­benzoic acid-κO)lanthanum(III)]-tri-μ-4-ethyl­benzoato]
title_full catena-Poly[[aqua­(4-ethyl­benzoic acid-κO)lanthanum(III)]-tri-μ-4-ethyl­benzoato]
title_fullStr catena-Poly[[aqua­(4-ethyl­benzoic acid-κO)lanthanum(III)]-tri-μ-4-ethyl­benzoato]
title_full_unstemmed catena-Poly[[aqua­(4-ethyl­benzoic acid-κO)lanthanum(III)]-tri-μ-4-ethyl­benzoato]
title_short catena-Poly[[aqua­(4-ethyl­benzoic acid-κO)lanthanum(III)]-tri-μ-4-ethyl­benzoato]
title_sort catena-poly[[aqua­(4-ethyl­benzoic acid-κo)lanthanum(iii)]-tri-μ-4-ethyl­benzoato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979983/
https://www.ncbi.nlm.nih.gov/pubmed/21579652
http://dx.doi.org/10.1107/S160053681000190X
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