4,6-Dimeth­oxy-2-(methyl­sulfan­yl)pyrimidinium chloride

In the title compound, C(7)H(11)N(2)O(2)S(+)·Cl(−), the 4,6-dimeth­oxy-2-(methyl­sulfan­yl)pyrimidinium cation is essentially planar (r.m.s. deviation = 0.043 Å). In the crystal, the anions and cations are connected by inter­molecular N—H⋯Cl and C—H⋯Cl hydrogen bonds, forming a two-dimensional netwo...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979986/
https://www.ncbi.nlm.nih.gov/pubmed/21579728
http://dx.doi.org/10.1107/S1600536809055779
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author Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Hemamalini, Madhukar
collection PubMed
description In the title compound, C(7)H(11)N(2)O(2)S(+)·Cl(−), the 4,6-dimeth­oxy-2-(methyl­sulfan­yl)pyrimidinium cation is essentially planar (r.m.s. deviation = 0.043 Å). In the crystal, the anions and cations are connected by inter­molecular N—H⋯Cl and C—H⋯Cl hydrogen bonds, forming a two-dimensional network parallel to (011). Adjacent networks are cross-linked via π–π inter­actions involving the pyrimidinium ring [centroid–centroid distance = 3.5501 (8) Å].
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spelling pubmed-29799862010-12-30 4,6-Dimeth­oxy-2-(methyl­sulfan­yl)pyrimidinium chloride Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(11)N(2)O(2)S(+)·Cl(−), the 4,6-dimeth­oxy-2-(methyl­sulfan­yl)pyrimidinium cation is essentially planar (r.m.s. deviation = 0.043 Å). In the crystal, the anions and cations are connected by inter­molecular N—H⋯Cl and C—H⋯Cl hydrogen bonds, forming a two-dimensional network parallel to (011). Adjacent networks are cross-linked via π–π inter­actions involving the pyrimidinium ring [centroid–centroid distance = 3.5501 (8) Å]. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979986/ /pubmed/21579728 http://dx.doi.org/10.1107/S1600536809055779 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hemamalini, Madhukar
Fun, Hoong-Kun
4,6-Dimeth­oxy-2-(methyl­sulfan­yl)pyrimidinium chloride
title 4,6-Dimeth­oxy-2-(methyl­sulfan­yl)pyrimidinium chloride
title_full 4,6-Dimeth­oxy-2-(methyl­sulfan­yl)pyrimidinium chloride
title_fullStr 4,6-Dimeth­oxy-2-(methyl­sulfan­yl)pyrimidinium chloride
title_full_unstemmed 4,6-Dimeth­oxy-2-(methyl­sulfan­yl)pyrimidinium chloride
title_short 4,6-Dimeth­oxy-2-(methyl­sulfan­yl)pyrimidinium chloride
title_sort 4,6-dimeth­oxy-2-(methyl­sulfan­yl)pyrimidinium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979986/
https://www.ncbi.nlm.nih.gov/pubmed/21579728
http://dx.doi.org/10.1107/S1600536809055779
work_keys_str_mv AT hemamalinimadhukar 46dimethoxy2methylsulfanylpyrimidiniumchloride
AT funhoongkun 46dimethoxy2methylsulfanylpyrimidiniumchloride

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