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Poly[[(N,N-dimethyl­formamide-κO)(μ(3)-pyrazine-2,3-dicarboxyl­ato-κ(4) N (1),O(2):O (3):O (3))copper(II)] monohydrate]

In the title compound, {[Cu(C(6)H(2)N(2)O(4))(C(3)H(7)NO)]·H(2)O}(n), the Cu(II) atom is coordinated by an N,O-bidentate pyrazine-2,3-dicarboxyl­ate (pzdc) dianion, two O atoms from two other pzdc anions and one O atom from the dimethlyformamide ligand, forming a distorted square-pyramidal CuNO(4) g...

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Detalles Bibliográficos
Autores principales: Fan, Zhen-Zhong, Wang, Guo-Ping, Li, Yu-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979988/
https://www.ncbi.nlm.nih.gov/pubmed/21579908
http://dx.doi.org/10.1107/S1600536809051332
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author Fan, Zhen-Zhong
Wang, Guo-Ping
Li, Yu-Sheng
author_facet Fan, Zhen-Zhong
Wang, Guo-Ping
Li, Yu-Sheng
author_sort Fan, Zhen-Zhong
collection PubMed
description In the title compound, {[Cu(C(6)H(2)N(2)O(4))(C(3)H(7)NO)]·H(2)O}(n), the Cu(II) atom is coordinated by an N,O-bidentate pyrazine-2,3-dicarboxyl­ate (pzdc) dianion, two O atoms from two other pzdc anions and one O atom from the dimethlyformamide ligand, forming a distorted square-pyramidal CuNO(4) geometry. The polymeric character of the structure is established by the formation of layers parallel to (100) via bridging pzdc ligands. O—H⋯O hydrogen bonding between water mol­ecules and uncoordinated carboxyl­ate O atoms leads to additional stabilization of the structure.
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spelling pubmed-29799882010-12-30 Poly[[(N,N-dimethyl­formamide-κO)(μ(3)-pyrazine-2,3-dicarboxyl­ato-κ(4) N (1),O(2):O (3):O (3))copper(II)] monohydrate] Fan, Zhen-Zhong Wang, Guo-Ping Li, Yu-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(C(6)H(2)N(2)O(4))(C(3)H(7)NO)]·H(2)O}(n), the Cu(II) atom is coordinated by an N,O-bidentate pyrazine-2,3-dicarboxyl­ate (pzdc) dianion, two O atoms from two other pzdc anions and one O atom from the dimethlyformamide ligand, forming a distorted square-pyramidal CuNO(4) geometry. The polymeric character of the structure is established by the formation of layers parallel to (100) via bridging pzdc ligands. O—H⋯O hydrogen bonding between water mol­ecules and uncoordinated carboxyl­ate O atoms leads to additional stabilization of the structure. International Union of Crystallography 2009-12-04 /pmc/articles/PMC2979988/ /pubmed/21579908 http://dx.doi.org/10.1107/S1600536809051332 Text en © Fan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fan, Zhen-Zhong
Wang, Guo-Ping
Li, Yu-Sheng
Poly[[(N,N-dimethyl­formamide-κO)(μ(3)-pyrazine-2,3-dicarboxyl­ato-κ(4) N (1),O(2):O (3):O (3))copper(II)] monohydrate]
title Poly[[(N,N-dimethyl­formamide-κO)(μ(3)-pyrazine-2,3-dicarboxyl­ato-κ(4) N (1),O(2):O (3):O (3))copper(II)] monohydrate]
title_full Poly[[(N,N-dimethyl­formamide-κO)(μ(3)-pyrazine-2,3-dicarboxyl­ato-κ(4) N (1),O(2):O (3):O (3))copper(II)] monohydrate]
title_fullStr Poly[[(N,N-dimethyl­formamide-κO)(μ(3)-pyrazine-2,3-dicarboxyl­ato-κ(4) N (1),O(2):O (3):O (3))copper(II)] monohydrate]
title_full_unstemmed Poly[[(N,N-dimethyl­formamide-κO)(μ(3)-pyrazine-2,3-dicarboxyl­ato-κ(4) N (1),O(2):O (3):O (3))copper(II)] monohydrate]
title_short Poly[[(N,N-dimethyl­formamide-κO)(μ(3)-pyrazine-2,3-dicarboxyl­ato-κ(4) N (1),O(2):O (3):O (3))copper(II)] monohydrate]
title_sort poly[[(n,n-dimethyl­formamide-κo)(μ(3)-pyrazine-2,3-dicarboxyl­ato-κ(4) n (1),o(2):o (3):o (3))copper(ii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979988/
https://www.ncbi.nlm.nih.gov/pubmed/21579908
http://dx.doi.org/10.1107/S1600536809051332
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