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Poly[[(N,N-dimethylformamide-κO)(μ(3)-pyrazine-2,3-dicarboxylato-κ(4) N (1),O(2):O (3):O (3))copper(II)] monohydrate]
In the title compound, {[Cu(C(6)H(2)N(2)O(4))(C(3)H(7)NO)]·H(2)O}(n), the Cu(II) atom is coordinated by an N,O-bidentate pyrazine-2,3-dicarboxylate (pzdc) dianion, two O atoms from two other pzdc anions and one O atom from the dimethlyformamide ligand, forming a distorted square-pyramidal CuNO(4) g...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979988/ https://www.ncbi.nlm.nih.gov/pubmed/21579908 http://dx.doi.org/10.1107/S1600536809051332 |
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author | Fan, Zhen-Zhong Wang, Guo-Ping Li, Yu-Sheng |
author_facet | Fan, Zhen-Zhong Wang, Guo-Ping Li, Yu-Sheng |
author_sort | Fan, Zhen-Zhong |
collection | PubMed |
description | In the title compound, {[Cu(C(6)H(2)N(2)O(4))(C(3)H(7)NO)]·H(2)O}(n), the Cu(II) atom is coordinated by an N,O-bidentate pyrazine-2,3-dicarboxylate (pzdc) dianion, two O atoms from two other pzdc anions and one O atom from the dimethlyformamide ligand, forming a distorted square-pyramidal CuNO(4) geometry. The polymeric character of the structure is established by the formation of layers parallel to (100) via bridging pzdc ligands. O—H⋯O hydrogen bonding between water molecules and uncoordinated carboxylate O atoms leads to additional stabilization of the structure. |
format | Text |
id | pubmed-2979988 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29799882010-12-30 Poly[[(N,N-dimethylformamide-κO)(μ(3)-pyrazine-2,3-dicarboxylato-κ(4) N (1),O(2):O (3):O (3))copper(II)] monohydrate] Fan, Zhen-Zhong Wang, Guo-Ping Li, Yu-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(C(6)H(2)N(2)O(4))(C(3)H(7)NO)]·H(2)O}(n), the Cu(II) atom is coordinated by an N,O-bidentate pyrazine-2,3-dicarboxylate (pzdc) dianion, two O atoms from two other pzdc anions and one O atom from the dimethlyformamide ligand, forming a distorted square-pyramidal CuNO(4) geometry. The polymeric character of the structure is established by the formation of layers parallel to (100) via bridging pzdc ligands. O—H⋯O hydrogen bonding between water molecules and uncoordinated carboxylate O atoms leads to additional stabilization of the structure. International Union of Crystallography 2009-12-04 /pmc/articles/PMC2979988/ /pubmed/21579908 http://dx.doi.org/10.1107/S1600536809051332 Text en © Fan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fan, Zhen-Zhong Wang, Guo-Ping Li, Yu-Sheng Poly[[(N,N-dimethylformamide-κO)(μ(3)-pyrazine-2,3-dicarboxylato-κ(4) N (1),O(2):O (3):O (3))copper(II)] monohydrate] |
title | Poly[[(N,N-dimethylformamide-κO)(μ(3)-pyrazine-2,3-dicarboxylato-κ(4)
N
(1),O(2):O
(3):O
(3))copper(II)] monohydrate] |
title_full | Poly[[(N,N-dimethylformamide-κO)(μ(3)-pyrazine-2,3-dicarboxylato-κ(4)
N
(1),O(2):O
(3):O
(3))copper(II)] monohydrate] |
title_fullStr | Poly[[(N,N-dimethylformamide-κO)(μ(3)-pyrazine-2,3-dicarboxylato-κ(4)
N
(1),O(2):O
(3):O
(3))copper(II)] monohydrate] |
title_full_unstemmed | Poly[[(N,N-dimethylformamide-κO)(μ(3)-pyrazine-2,3-dicarboxylato-κ(4)
N
(1),O(2):O
(3):O
(3))copper(II)] monohydrate] |
title_short | Poly[[(N,N-dimethylformamide-κO)(μ(3)-pyrazine-2,3-dicarboxylato-κ(4)
N
(1),O(2):O
(3):O
(3))copper(II)] monohydrate] |
title_sort | poly[[(n,n-dimethylformamide-κo)(μ(3)-pyrazine-2,3-dicarboxylato-κ(4)
n
(1),o(2):o
(3):o
(3))copper(ii)] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979988/ https://www.ncbi.nlm.nih.gov/pubmed/21579908 http://dx.doi.org/10.1107/S1600536809051332 |
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