Tris(ethane-1,2-diamine-κ(2) N,N′)nickel(II) diiodide

The title compound, [Ni(C(2)H(8)N(2))(3)]I(2), crystallizes with an [Ni(en)(3) (2+)] cation (en is ethane-1,2-diamine) and two iodide ions in the asymmetric unit. Two of the en ligands surrrounding the Ni(2+) ion have disordered C atoms, while the third exhibits extensive weak N—H⋯I inter­actions wi...

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Detalles Bibliográficos
Autores principales: Brewer, Greg, Butcher, Ray J., Jasinski, Jerry P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979990/
https://www.ncbi.nlm.nih.gov/pubmed/21579912
http://dx.doi.org/10.1107/S1600536809054580
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author Brewer, Greg
Butcher, Ray J.
Jasinski, Jerry P.
author_facet Brewer, Greg
Butcher, Ray J.
Jasinski, Jerry P.
author_sort Brewer, Greg
collection PubMed
description The title compound, [Ni(C(2)H(8)N(2))(3)]I(2), crystallizes with an [Ni(en)(3) (2+)] cation (en is ethane-1,2-diamine) and two iodide ions in the asymmetric unit. Two of the en ligands surrrounding the Ni(2+) ion have disordered C atoms, while the third exhibits extensive weak N—H⋯I inter­actions with the two iodide ions that extend throughout the crystalline lattice, producing an infinite network along (011).
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spelling pubmed-29799902010-12-30 Tris(ethane-1,2-diamine-κ(2) N,N′)nickel(II) diiodide Brewer, Greg Butcher, Ray J. Jasinski, Jerry P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(2)H(8)N(2))(3)]I(2), crystallizes with an [Ni(en)(3) (2+)] cation (en is ethane-1,2-diamine) and two iodide ions in the asymmetric unit. Two of the en ligands surrrounding the Ni(2+) ion have disordered C atoms, while the third exhibits extensive weak N—H⋯I inter­actions with the two iodide ions that extend throughout the crystalline lattice, producing an infinite network along (011). International Union of Crystallography 2009-12-24 /pmc/articles/PMC2979990/ /pubmed/21579912 http://dx.doi.org/10.1107/S1600536809054580 Text en © Brewer et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Brewer, Greg
Butcher, Ray J.
Jasinski, Jerry P.
Tris(ethane-1,2-diamine-κ(2) N,N′)nickel(II) diiodide
title Tris(ethane-1,2-diamine-κ(2) N,N′)nickel(II) diiodide
title_full Tris(ethane-1,2-diamine-κ(2) N,N′)nickel(II) diiodide
title_fullStr Tris(ethane-1,2-diamine-κ(2) N,N′)nickel(II) diiodide
title_full_unstemmed Tris(ethane-1,2-diamine-κ(2) N,N′)nickel(II) diiodide
title_short Tris(ethane-1,2-diamine-κ(2) N,N′)nickel(II) diiodide
title_sort tris(ethane-1,2-diamine-κ(2) n,n′)nickel(ii) diiodide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979990/
https://www.ncbi.nlm.nih.gov/pubmed/21579912
http://dx.doi.org/10.1107/S1600536809054580
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AT butcherrayj trisethane12diaminek2nnnickeliidiiodide
AT jasinskijerryp trisethane12diaminek2nnnickeliidiiodide

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