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Bis(μ-4-hydroxybenzoato-κ(2) O:O′)bis[triaquabis(4-hydroxybenzoato)-κO;κ(2) O,O′-terbium(III)] decahydrate
The title dinuclear compound, [Tb(2)(C(7)H(5)O(3))(6)(H(2)O)(6)]·10H(2)O, lies on a center of inversion and the two Tb(III) atoms are bridged by two 4-hydroxybenzoate anions; each metal atom is further coordinated by one monodentate anion and chelated by the third anion. The eight-coordinate geomet...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979992/ https://www.ncbi.nlm.nih.gov/pubmed/21579951 http://dx.doi.org/10.1107/S1600536809052489 |
| _version_ | 1782191551402737664 |
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| author | Zhu, Yi-Min Feng, Pei-Pei Yang, Yang-Yi Ng, Seik Weng |
| author_facet | Zhu, Yi-Min Feng, Pei-Pei Yang, Yang-Yi Ng, Seik Weng |
| author_sort | Zhu, Yi-Min |
| collection | PubMed |
| description | The title dinuclear compound, [Tb(2)(C(7)H(5)O(3))(6)(H(2)O)(6)]·10H(2)O, lies on a center of inversion and the two Tb(III) atoms are bridged by two 4-hydroxybenzoate anions; each metal atom is further coordinated by one monodentate anion and chelated by the third anion. The eight-coordinate geometry approximates a square antiprism. Hydrogen bonds of the O—H⋯O type connect the uncoordinated water molecules to the dinuclear species, forming a three-dimensional network. |
| format | Text |
| id | pubmed-2979992 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29799922010-12-30 Bis(μ-4-hydroxybenzoato-κ(2) O:O′)bis[triaquabis(4-hydroxybenzoato)-κO;κ(2) O,O′-terbium(III)] decahydrate Zhu, Yi-Min Feng, Pei-Pei Yang, Yang-Yi Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title dinuclear compound, [Tb(2)(C(7)H(5)O(3))(6)(H(2)O)(6)]·10H(2)O, lies on a center of inversion and the two Tb(III) atoms are bridged by two 4-hydroxybenzoate anions; each metal atom is further coordinated by one monodentate anion and chelated by the third anion. The eight-coordinate geometry approximates a square antiprism. Hydrogen bonds of the O—H⋯O type connect the uncoordinated water molecules to the dinuclear species, forming a three-dimensional network. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2979992/ /pubmed/21579951 http://dx.doi.org/10.1107/S1600536809052489 Text en © Zhu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhu, Yi-Min Feng, Pei-Pei Yang, Yang-Yi Ng, Seik Weng Bis(μ-4-hydroxybenzoato-κ(2) O:O′)bis[triaquabis(4-hydroxybenzoato)-κO;κ(2) O,O′-terbium(III)] decahydrate |
| title | Bis(μ-4-hydroxybenzoato-κ(2)
O:O′)bis[triaquabis(4-hydroxybenzoato)-κO;κ(2)
O,O′-terbium(III)] decahydrate |
| title_full | Bis(μ-4-hydroxybenzoato-κ(2)
O:O′)bis[triaquabis(4-hydroxybenzoato)-κO;κ(2)
O,O′-terbium(III)] decahydrate |
| title_fullStr | Bis(μ-4-hydroxybenzoato-κ(2)
O:O′)bis[triaquabis(4-hydroxybenzoato)-κO;κ(2)
O,O′-terbium(III)] decahydrate |
| title_full_unstemmed | Bis(μ-4-hydroxybenzoato-κ(2)
O:O′)bis[triaquabis(4-hydroxybenzoato)-κO;κ(2)
O,O′-terbium(III)] decahydrate |
| title_short | Bis(μ-4-hydroxybenzoato-κ(2)
O:O′)bis[triaquabis(4-hydroxybenzoato)-κO;κ(2)
O,O′-terbium(III)] decahydrate |
| title_sort | bis(μ-4-hydroxybenzoato-κ(2)
o:o′)bis[triaquabis(4-hydroxybenzoato)-κo;κ(2)
o,o′-terbium(iii)] decahydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979992/ https://www.ncbi.nlm.nih.gov/pubmed/21579951 http://dx.doi.org/10.1107/S1600536809052489 |
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