5α-Androst-3-en-17β-yl acetate

In the crystal structure of the title compound, C(21)H(32)O(2), ring A is highly distorted, with a conformation inter­mediate between 10β-sofa and 1α,10β-half chair; rings B and C have slightly flattened chair conformations. Ring D assumes an unusual 13β-envelope conformation, probably induced by th...

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Detalles Bibliográficos
Autores principales: Andrade, L. C. R., Paixão, J. A., de Almeida, M. J. M., Tavares da Silva, E. J., Fernandes Roleira, F. M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979999/
https://www.ncbi.nlm.nih.gov/pubmed/21580068
http://dx.doi.org/10.1107/S1600536809053264
Descripción
Sumario:In the crystal structure of the title compound, C(21)H(32)O(2), ring A is highly distorted, with a conformation inter­mediate between 10β-sofa and 1α,10β-half chair; rings B and C have slightly flattened chair conformations. Ring D assumes an unusual 13β-envelope conformation, probably induced by the acet­oxy substituent. Cohesion of the crystal structure is due only to weak van der Waals inter­actions.

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