Aqua­bis(2,3-dimethyl-4-oxo-4H-pyrido[1,2-a]pyrimidin-9-olato)nickel(II)

In the crystal structure of the mononuclear title complex, [Ni(C(10)H(9)N(2)O(2))(2)(H(2)O)], the Ni(II) ion is five-coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from 2,3-dimethyl-4-oxopyrido[1,2-a]pyrimidin-9-olate ligands and one O atom from a water mol­ecule...

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Detalles Bibliográficos
Autores principales: Zhang, Huaihong, Sun, Yu, Chen, Xiaodan, Yu, Fei, Zou, Zhihong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980000/
https://www.ncbi.nlm.nih.gov/pubmed/21579947
http://dx.doi.org/10.1107/S1600536809051563
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author Zhang, Huaihong
Sun, Yu
Chen, Xiaodan
Yu, Fei
Zou, Zhihong
author_facet Zhang, Huaihong
Sun, Yu
Chen, Xiaodan
Yu, Fei
Zou, Zhihong
author_sort Zhang, Huaihong
collection PubMed
description In the crystal structure of the mononuclear title complex, [Ni(C(10)H(9)N(2)O(2))(2)(H(2)O)], the Ni(II) ion is five-coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from 2,3-dimethyl-4-oxopyrido[1,2-a]pyrimidin-9-olate ligands and one O atom from a water mol­ecule. O—H⋯O hydrogen bonds between the coordinated water mol­ecule and the ligand connect adjacent mol­ecules, forming a ribbon parallel to the b axis.
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spelling pubmed-29800002010-12-30 Aqua­bis(2,3-dimethyl-4-oxo-4H-pyrido[1,2-a]pyrimidin-9-olato)nickel(II) Zhang, Huaihong Sun, Yu Chen, Xiaodan Yu, Fei Zou, Zhihong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the mononuclear title complex, [Ni(C(10)H(9)N(2)O(2))(2)(H(2)O)], the Ni(II) ion is five-coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from 2,3-dimethyl-4-oxopyrido[1,2-a]pyrimidin-9-olate ligands and one O atom from a water mol­ecule. O—H⋯O hydrogen bonds between the coordinated water mol­ecule and the ligand connect adjacent mol­ecules, forming a ribbon parallel to the b axis. International Union of Crystallography 2009-12-04 /pmc/articles/PMC2980000/ /pubmed/21579947 http://dx.doi.org/10.1107/S1600536809051563 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Huaihong
Sun, Yu
Chen, Xiaodan
Yu, Fei
Zou, Zhihong
Aqua­bis(2,3-dimethyl-4-oxo-4H-pyrido[1,2-a]pyrimidin-9-olato)nickel(II)
title Aqua­bis(2,3-dimethyl-4-oxo-4H-pyrido[1,2-a]pyrimidin-9-olato)nickel(II)
title_full Aqua­bis(2,3-dimethyl-4-oxo-4H-pyrido[1,2-a]pyrimidin-9-olato)nickel(II)
title_fullStr Aqua­bis(2,3-dimethyl-4-oxo-4H-pyrido[1,2-a]pyrimidin-9-olato)nickel(II)
title_full_unstemmed Aqua­bis(2,3-dimethyl-4-oxo-4H-pyrido[1,2-a]pyrimidin-9-olato)nickel(II)
title_short Aqua­bis(2,3-dimethyl-4-oxo-4H-pyrido[1,2-a]pyrimidin-9-olato)nickel(II)
title_sort aqua­bis(2,3-dimethyl-4-oxo-4h-pyrido[1,2-a]pyrimidin-9-olato)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980000/
https://www.ncbi.nlm.nih.gov/pubmed/21579947
http://dx.doi.org/10.1107/S1600536809051563
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