An inter­molecular dative B←N bond in 5-(4,4,5,5-tetra­methyl-1,3,2-dioxa­borolan-2-yl)-1,3-thia­zole

The title compound, C(9)H(14)BNO(2)S, is in an unusual bend conformation and the B atom of one mol­ecule within the crystal forms an inter­molecular dative bond with the N atom of a neighbouring mol­ecule, an infrequent phenomenon in boronic derivative crystals.

Detalles Bibliográficos
Autores principales: Sopková-de Oliveira Santos, Jana, Primas, Nicolas, Lohier, Jean-François, Bouillon, Alexandre, Rault, Sylvain
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980002/
https://www.ncbi.nlm.nih.gov/pubmed/21580045
http://dx.doi.org/10.1107/S1600536809052775
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author Sopková-de Oliveira Santos, Jana
Primas, Nicolas
Lohier, Jean-François
Bouillon, Alexandre
Rault, Sylvain
author_facet Sopková-de Oliveira Santos, Jana
Primas, Nicolas
Lohier, Jean-François
Bouillon, Alexandre
Rault, Sylvain
author_sort Sopková-de Oliveira Santos, Jana
collection PubMed
description The title compound, C(9)H(14)BNO(2)S, is in an unusual bend conformation and the B atom of one mol­ecule within the crystal forms an inter­molecular dative bond with the N atom of a neighbouring mol­ecule, an infrequent phenomenon in boronic derivative crystals.
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spelling pubmed-29800022010-12-30 An inter­molecular dative B←N bond in 5-(4,4,5,5-tetra­methyl-1,3,2-dioxa­borolan-2-yl)-1,3-thia­zole Sopková-de Oliveira Santos, Jana Primas, Nicolas Lohier, Jean-François Bouillon, Alexandre Rault, Sylvain Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(14)BNO(2)S, is in an unusual bend conformation and the B atom of one mol­ecule within the crystal forms an inter­molecular dative bond with the N atom of a neighbouring mol­ecule, an infrequent phenomenon in boronic derivative crystals. International Union of Crystallography 2009-12-16 /pmc/articles/PMC2980002/ /pubmed/21580045 http://dx.doi.org/10.1107/S1600536809052775 Text en © Sopková-de Oliveira Santos et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sopková-de Oliveira Santos, Jana
Primas, Nicolas
Lohier, Jean-François
Bouillon, Alexandre
Rault, Sylvain
An inter­molecular dative B←N bond in 5-(4,4,5,5-tetra­methyl-1,3,2-dioxa­borolan-2-yl)-1,3-thia­zole
title An inter­molecular dative B←N bond in 5-(4,4,5,5-tetra­methyl-1,3,2-dioxa­borolan-2-yl)-1,3-thia­zole
title_full An inter­molecular dative B←N bond in 5-(4,4,5,5-tetra­methyl-1,3,2-dioxa­borolan-2-yl)-1,3-thia­zole
title_fullStr An inter­molecular dative B←N bond in 5-(4,4,5,5-tetra­methyl-1,3,2-dioxa­borolan-2-yl)-1,3-thia­zole
title_full_unstemmed An inter­molecular dative B←N bond in 5-(4,4,5,5-tetra­methyl-1,3,2-dioxa­borolan-2-yl)-1,3-thia­zole
title_short An inter­molecular dative B←N bond in 5-(4,4,5,5-tetra­methyl-1,3,2-dioxa­borolan-2-yl)-1,3-thia­zole
title_sort inter­molecular dative b←n bond in 5-(4,4,5,5-tetra­methyl-1,3,2-dioxa­borolan-2-yl)-1,3-thia­zole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980002/
https://www.ncbi.nlm.nih.gov/pubmed/21580045
http://dx.doi.org/10.1107/S1600536809052775
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