Bis[2-meth­oxy-6-(3-pyridylmethyl­imino­meth­yl)phenolato-κ(2) N,O]copper(II)

In the title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) ion is located on a crystallographic inversion center. The complex thus adopts a square-planar trans-[CuN(2)O(2)] coordination geometry, with the Cu(II) ion coordinated by two 2-meth­oxy-6-(3-pyridylmethyl­imino­meth­yl)phenolate (Schiff...

Descripción completa

Detalles Bibliográficos
Autores principales: Chen, Xiaodan, Sun, Yu, Yao, Qingzhao, Zhang, Huaihong, Liang, Qing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980013/
https://www.ncbi.nlm.nih.gov/pubmed/21579937
http://dx.doi.org/10.1107/S1600536809052349
Descripción
Sumario:In the title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) ion is located on a crystallographic inversion center. The complex thus adopts a square-planar trans-[CuN(2)O(2)] coordination geometry, with the Cu(II) ion coordinated by two 2-meth­oxy-6-(3-pyridylmethyl­imino­meth­yl)phenolate (Schiff base) ligands. The aryl and pyridyl rings in the Schiff base are almost perpendicular to each other, with a dihedral angle of 87.61 (6)° between the planes of the two six-membered rings. The pyridyl ring was refined using a disorder model with approximately 70% occupancy for the major component

Ejemplares similares