Bis[2-meth­oxy-6-(3-pyridylmethyl­imino­meth­yl)phenolato-κ(2) N,O]copper(II)

In the title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) ion is located on a crystallographic inversion center. The complex thus adopts a square-planar trans-[CuN(2)O(2)] coordination geometry, with the Cu(II) ion coordinated by two 2-meth­oxy-6-(3-pyridylmethyl­imino­meth­yl)phenolate (Schiff...

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Detalles Bibliográficos
Autores principales: Chen, Xiaodan, Sun, Yu, Yao, Qingzhao, Zhang, Huaihong, Liang, Qing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980013/
https://www.ncbi.nlm.nih.gov/pubmed/21579937
http://dx.doi.org/10.1107/S1600536809052349
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author Chen, Xiaodan
Sun, Yu
Yao, Qingzhao
Zhang, Huaihong
Liang, Qing
author_facet Chen, Xiaodan
Sun, Yu
Yao, Qingzhao
Zhang, Huaihong
Liang, Qing
author_sort Chen, Xiaodan
collection PubMed
description In the title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) ion is located on a crystallographic inversion center. The complex thus adopts a square-planar trans-[CuN(2)O(2)] coordination geometry, with the Cu(II) ion coordinated by two 2-meth­oxy-6-(3-pyridylmethyl­imino­meth­yl)phenolate (Schiff base) ligands. The aryl and pyridyl rings in the Schiff base are almost perpendicular to each other, with a dihedral angle of 87.61 (6)° between the planes of the two six-membered rings. The pyridyl ring was refined using a disorder model with approximately 70% occupancy for the major component
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spelling pubmed-29800132010-12-30 Bis[2-meth­oxy-6-(3-pyridylmethyl­imino­meth­yl)phenolato-κ(2) N,O]copper(II) Chen, Xiaodan Sun, Yu Yao, Qingzhao Zhang, Huaihong Liang, Qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) ion is located on a crystallographic inversion center. The complex thus adopts a square-planar trans-[CuN(2)O(2)] coordination geometry, with the Cu(II) ion coordinated by two 2-meth­oxy-6-(3-pyridylmethyl­imino­meth­yl)phenolate (Schiff base) ligands. The aryl and pyridyl rings in the Schiff base are almost perpendicular to each other, with a dihedral angle of 87.61 (6)° between the planes of the two six-membered rings. The pyridyl ring was refined using a disorder model with approximately 70% occupancy for the major component International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980013/ /pubmed/21579937 http://dx.doi.org/10.1107/S1600536809052349 Text en © Chen et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Xiaodan
Sun, Yu
Yao, Qingzhao
Zhang, Huaihong
Liang, Qing
Bis[2-meth­oxy-6-(3-pyridylmethyl­imino­meth­yl)phenolato-κ(2) N,O]copper(II)
title Bis[2-meth­oxy-6-(3-pyridylmethyl­imino­meth­yl)phenolato-κ(2) N,O]copper(II)
title_full Bis[2-meth­oxy-6-(3-pyridylmethyl­imino­meth­yl)phenolato-κ(2) N,O]copper(II)
title_fullStr Bis[2-meth­oxy-6-(3-pyridylmethyl­imino­meth­yl)phenolato-κ(2) N,O]copper(II)
title_full_unstemmed Bis[2-meth­oxy-6-(3-pyridylmethyl­imino­meth­yl)phenolato-κ(2) N,O]copper(II)
title_short Bis[2-meth­oxy-6-(3-pyridylmethyl­imino­meth­yl)phenolato-κ(2) N,O]copper(II)
title_sort bis[2-meth­oxy-6-(3-pyridylmethyl­imino­meth­yl)phenolato-κ(2) n,o]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980013/
https://www.ncbi.nlm.nih.gov/pubmed/21579937
http://dx.doi.org/10.1107/S1600536809052349
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AT yaoqingzhao bis2methoxy63pyridylmethyliminomethylphenolatok2nocopperii
AT zhanghuaihong bis2methoxy63pyridylmethyliminomethylphenolatok2nocopperii
AT liangqing bis2methoxy63pyridylmethyliminomethylphenolatok2nocopperii

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