catena-Poly[[trimethyl­tin(IV)]-μ-cyclo­hex-3-ene-1-carboxyl­ato]

The title compound, [Sn(CH(3))(3)(C(7)H(9)O(2))](n), forms an extended zigzag chain structure propagating parallel to [010]. The Sn atom is in a slightly distorted trigonal-bipyramidal coordination environment with two carboxyl­ate O atoms in the axial and the three methyl groups in equatorial sites...

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Detalles Bibliográficos
Autores principales: Ren, Yun, Zhang, Rufen, Shi, Yang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980015/
https://www.ncbi.nlm.nih.gov/pubmed/21579982
http://dx.doi.org/10.1107/S1600536809054403
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author Ren, Yun
Zhang, Rufen
Shi, Yang
author_facet Ren, Yun
Zhang, Rufen
Shi, Yang
author_sort Ren, Yun
collection PubMed
description The title compound, [Sn(CH(3))(3)(C(7)H(9)O(2))](n), forms an extended zigzag chain structure propagating parallel to [010]. The Sn atom is in a slightly distorted trigonal-bipyramidal coordination environment with two carboxyl­ate O atoms in the axial and the three methyl groups in equatorial sites. The cyclo­hexene ring has a distorted half-boat conformation. There is an intra­molecular C—H⋯O hydrogen bond.
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spelling pubmed-29800152010-12-30 catena-Poly[[trimethyl­tin(IV)]-μ-cyclo­hex-3-ene-1-carboxyl­ato] Ren, Yun Zhang, Rufen Shi, Yang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(CH(3))(3)(C(7)H(9)O(2))](n), forms an extended zigzag chain structure propagating parallel to [010]. The Sn atom is in a slightly distorted trigonal-bipyramidal coordination environment with two carboxyl­ate O atoms in the axial and the three methyl groups in equatorial sites. The cyclo­hexene ring has a distorted half-boat conformation. There is an intra­molecular C—H⋯O hydrogen bond. International Union of Crystallography 2009-12-24 /pmc/articles/PMC2980015/ /pubmed/21579982 http://dx.doi.org/10.1107/S1600536809054403 Text en © Ren et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ren, Yun
Zhang, Rufen
Shi, Yang
catena-Poly[[trimethyl­tin(IV)]-μ-cyclo­hex-3-ene-1-carboxyl­ato]
title catena-Poly[[trimethyl­tin(IV)]-μ-cyclo­hex-3-ene-1-carboxyl­ato]
title_full catena-Poly[[trimethyl­tin(IV)]-μ-cyclo­hex-3-ene-1-carboxyl­ato]
title_fullStr catena-Poly[[trimethyl­tin(IV)]-μ-cyclo­hex-3-ene-1-carboxyl­ato]
title_full_unstemmed catena-Poly[[trimethyl­tin(IV)]-μ-cyclo­hex-3-ene-1-carboxyl­ato]
title_short catena-Poly[[trimethyl­tin(IV)]-μ-cyclo­hex-3-ene-1-carboxyl­ato]
title_sort catena-poly[[trimethyl­tin(iv)]-μ-cyclo­hex-3-ene-1-carboxyl­ato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980015/
https://www.ncbi.nlm.nih.gov/pubmed/21579982
http://dx.doi.org/10.1107/S1600536809054403
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AT shiyang catenapolytrimethyltinivmcyclohex3ene1carboxylato

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