Tris[2-meth­oxy-6-(4-methyl­phenyl­iminio­meth­yl)phenolato-κ(2) O,O′]tris­(thio­cyanato-κN)neodymium(III)

In the title compound, [Nd(NCS)(3)(C(15)H(15)NO(2))(3)], the Nd(III) ion is coordinated by three thio­cyanate anions [Nd—N = 2.489 (8)–2.530 (7) Å] and six O atoms [Nd—O = 2.375 (4)–2.843 (5) Å] from three zwitterionic 2-meth­oxy-6-(4-methyl­phenyl­iminiometh­yl)phenolate ligands in a tricapped trig...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Jia-Lu, Shen, Jin-Bei, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980016/
https://www.ncbi.nlm.nih.gov/pubmed/21579967
http://dx.doi.org/10.1107/S1600536809053124
Descripción
Sumario:In the title compound, [Nd(NCS)(3)(C(15)H(15)NO(2))(3)], the Nd(III) ion is coordinated by three thio­cyanate anions [Nd—N = 2.489 (8)–2.530 (7) Å] and six O atoms [Nd—O = 2.375 (4)–2.843 (5) Å] from three zwitterionic 2-meth­oxy-6-(4-methyl­phenyl­iminiometh­yl)phenolate ligands in a tricapped trigonal-prismatic geometry. Intra­molecular N—H⋯O hydrogen bonds occur. The crystal packing exhibits weak inter­molecular C—H⋯S hydrogen bonds, π–π inter­actions with a distance of 3.904 (7) Å between the centroids of the aromatic rings, and voids of 101 Å(3).

Ejemplares similares