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Tris[2-methoxy-6-(4-methylphenyliminiomethyl)phenolato-κ(2) O,O′]tris(thiocyanato-κN)neodymium(III)
In the title compound, [Nd(NCS)(3)(C(15)H(15)NO(2))(3)], the Nd(III) ion is coordinated by three thiocyanate anions [Nd—N = 2.489 (8)–2.530 (7) Å] and six O atoms [Nd—O = 2.375 (4)–2.843 (5) Å] from three zwitterionic 2-methoxy-6-(4-methylphenyliminiomethyl)phenolate ligands in a tricapped trig...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980016/ https://www.ncbi.nlm.nih.gov/pubmed/21579967 http://dx.doi.org/10.1107/S1600536809053124 |
| _version_ | 1782191557284200448 |
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| author | Liu, Jia-Lu Shen, Jin-Bei Zhao, Guo-Liang |
| author_facet | Liu, Jia-Lu Shen, Jin-Bei Zhao, Guo-Liang |
| author_sort | Liu, Jia-Lu |
| collection | PubMed |
| description | In the title compound, [Nd(NCS)(3)(C(15)H(15)NO(2))(3)], the Nd(III) ion is coordinated by three thiocyanate anions [Nd—N = 2.489 (8)–2.530 (7) Å] and six O atoms [Nd—O = 2.375 (4)–2.843 (5) Å] from three zwitterionic 2-methoxy-6-(4-methylphenyliminiomethyl)phenolate ligands in a tricapped trigonal-prismatic geometry. Intramolecular N—H⋯O hydrogen bonds occur. The crystal packing exhibits weak intermolecular C—H⋯S hydrogen bonds, π–π interactions with a distance of 3.904 (7) Å between the centroids of the aromatic rings, and voids of 101 Å(3). |
| format | Text |
| id | pubmed-2980016 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29800162010-12-30 Tris[2-methoxy-6-(4-methylphenyliminiomethyl)phenolato-κ(2) O,O′]tris(thiocyanato-κN)neodymium(III) Liu, Jia-Lu Shen, Jin-Bei Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Nd(NCS)(3)(C(15)H(15)NO(2))(3)], the Nd(III) ion is coordinated by three thiocyanate anions [Nd—N = 2.489 (8)–2.530 (7) Å] and six O atoms [Nd—O = 2.375 (4)–2.843 (5) Å] from three zwitterionic 2-methoxy-6-(4-methylphenyliminiomethyl)phenolate ligands in a tricapped trigonal-prismatic geometry. Intramolecular N—H⋯O hydrogen bonds occur. The crystal packing exhibits weak intermolecular C—H⋯S hydrogen bonds, π–π interactions with a distance of 3.904 (7) Å between the centroids of the aromatic rings, and voids of 101 Å(3). International Union of Crystallography 2009-12-16 /pmc/articles/PMC2980016/ /pubmed/21579967 http://dx.doi.org/10.1107/S1600536809053124 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Jia-Lu Shen, Jin-Bei Zhao, Guo-Liang Tris[2-methoxy-6-(4-methylphenyliminiomethyl)phenolato-κ(2) O,O′]tris(thiocyanato-κN)neodymium(III) |
| title | Tris[2-methoxy-6-(4-methylphenyliminiomethyl)phenolato-κ(2)
O,O′]tris(thiocyanato-κN)neodymium(III) |
| title_full | Tris[2-methoxy-6-(4-methylphenyliminiomethyl)phenolato-κ(2)
O,O′]tris(thiocyanato-κN)neodymium(III) |
| title_fullStr | Tris[2-methoxy-6-(4-methylphenyliminiomethyl)phenolato-κ(2)
O,O′]tris(thiocyanato-κN)neodymium(III) |
| title_full_unstemmed | Tris[2-methoxy-6-(4-methylphenyliminiomethyl)phenolato-κ(2)
O,O′]tris(thiocyanato-κN)neodymium(III) |
| title_short | Tris[2-methoxy-6-(4-methylphenyliminiomethyl)phenolato-κ(2)
O,O′]tris(thiocyanato-κN)neodymium(III) |
| title_sort | tris[2-methoxy-6-(4-methylphenyliminiomethyl)phenolato-κ(2)
o,o′]tris(thiocyanato-κn)neodymium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980016/ https://www.ncbi.nlm.nih.gov/pubmed/21579967 http://dx.doi.org/10.1107/S1600536809053124 |
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