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(5′′E)-1′′-Benzyl-1′-methyl-5′′-[4-(methylsulfanyl)benzylidene]-4′-[4-(methylsulfanyl)phenyl]dispiro[indoline-3,2′-pyrrolidine-3′,3′′-piperidine]-2,4′′-dione dichloromethane solvate
In the title compound, C(38)H(36)N(3)O(2)S(2)·CH(2)Cl(2), the 2-oxindole ring is almost planar (r.m.s. deviation = 0.032 Å), the pyrrolidine ring adopts a twist conformation and the piperidone ring exists as a chair. Three short C—H⋯O intramolecular contacts occur. In the crystal, molecules are li...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980017/ https://www.ncbi.nlm.nih.gov/pubmed/21580125 http://dx.doi.org/10.1107/S1600536809054774 |
Sumario: | In the title compound, C(38)H(36)N(3)O(2)S(2)·CH(2)Cl(2), the 2-oxindole ring is almost planar (r.m.s. deviation = 0.032 Å), the pyrrolidine ring adopts a twist conformation and the piperidone ring exists as a chair. Three short C—H⋯O intramolecular contacts occur. In the crystal, molecules are linked by C—H⋯O and C—H⋯N interactions. The dichloromethane solvent molecule is disordered over two orientations in a 0.765 (11):0.235 (11) ratio. |
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