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LaZnB(5)O(10), the first lanthanum zinc borate

Lanthanum zinc penta­borate, LaZnB(5)O(10), was synthesized by flux-supported solid-state reaction. It is a member of the LnMB(5)O(10) (Ln = rare earth ion and M = divalent metal ion) structure type. The crystal shows a three-dimensional structure constructed from two-dimensional {[B(5)O(10)](5−)}(n...

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Detalles Bibliográficos
Autores principales: Jiao, Zhi-Wei, Wang, Ru-Ji, Wang, Xiao-Qing, Shen, De-Zhong, Shen, Guang-Qiu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980020/
https://www.ncbi.nlm.nih.gov/pubmed/21579905
http://dx.doi.org/10.1107/S1600536809050922
Descripción
Sumario:Lanthanum zinc penta­borate, LaZnB(5)O(10), was synthesized by flux-supported solid-state reaction. It is a member of the LnMB(5)O(10) (Ln = rare earth ion and M = divalent metal ion) structure type. The crystal shows a three-dimensional structure constructed from two-dimensional {[B(5)O(10)](5−)}(n) layers with the lanthanum (coordination number nine) and zinc (coordination number six) ions filling in the inter­layers.