Dibromido(1,10-phenanthroline-κ(2) N,N′)palladium(II)

In the title complex, [PdBr(2)(C(12)H(8)N(2))], the Pd(II) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two bromide ions. The complex displays numerous inter­molecular π–π inter­actions between adjacent six-m...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980023/
https://www.ncbi.nlm.nih.gov/pubmed/21579964
http://dx.doi.org/10.1107/S160053680905168X
Descripción
Sumario:In the title complex, [PdBr(2)(C(12)H(8)N(2))], the Pd(II) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two bromide ions. The complex displays numerous inter­molecular π–π inter­actions between adjacent six-membered rings, the shortest centroid–centroid distance being 3.680 (4) Å. The nearly planar [maximum deviation 0.143 (2) Å] mol­ecules stack in columns parallel to (101) with a Pd⋯Pd distance of 4.8466 (9) Å.

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