Bis(propan-2-yl) [(1S)-1-(4-fluoro­phen­yl)-1-hydr­oxy-2-nitro­ethyl]phospho­nate

In the title compound, C(14)H(21)FNO(6)P, a staggered conformation about the central P—C bond occurs, with the oxo and hydroxyl groups occupying diagonally opposite positions. The crystal structure features supra­molecular chains mediated by O—H⋯O hydrogen bonds, which propagate in the a-axis direct...

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Detalles Bibliográficos
Autores principales: Mandal, Tanmay, Samanta, Sampak, Broker, Grant A., Zhao, Cong-Gui, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980027/
https://www.ncbi.nlm.nih.gov/pubmed/21580194
http://dx.doi.org/10.1107/S160053680905260X
Descripción
Sumario:In the title compound, C(14)H(21)FNO(6)P, a staggered conformation about the central P—C bond occurs, with the oxo and hydroxyl groups occupying diagonally opposite positions. The crystal structure features supra­molecular chains mediated by O—H⋯O hydrogen bonds, which propagate in the a-axis direction. A C—H⋯O inter­action consolidates the chains. Disorder was resolved for one of the isopropyl groups with a 0.60 (2):0.40 (2) occupancy ratio for the two components.

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