Bis(propan-2-yl) [(1S)-1-(4-fluoro­phen­yl)-1-hydr­oxy-2-nitro­ethyl]phospho­nate

In the title compound, C(14)H(21)FNO(6)P, a staggered conformation about the central P—C bond occurs, with the oxo and hydroxyl groups occupying diagonally opposite positions. The crystal structure features supra­molecular chains mediated by O—H⋯O hydrogen bonds, which propagate in the a-axis direct...

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Detalles Bibliográficos
Autores principales: Mandal, Tanmay, Samanta, Sampak, Broker, Grant A., Zhao, Cong-Gui, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980027/
https://www.ncbi.nlm.nih.gov/pubmed/21580194
http://dx.doi.org/10.1107/S160053680905260X
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author Mandal, Tanmay
Samanta, Sampak
Broker, Grant A.
Zhao, Cong-Gui
Tiekink, Edward R. T.
author_facet Mandal, Tanmay
Samanta, Sampak
Broker, Grant A.
Zhao, Cong-Gui
Tiekink, Edward R. T.
author_sort Mandal, Tanmay
collection PubMed
description In the title compound, C(14)H(21)FNO(6)P, a staggered conformation about the central P—C bond occurs, with the oxo and hydroxyl groups occupying diagonally opposite positions. The crystal structure features supra­molecular chains mediated by O—H⋯O hydrogen bonds, which propagate in the a-axis direction. A C—H⋯O inter­action consolidates the chains. Disorder was resolved for one of the isopropyl groups with a 0.60 (2):0.40 (2) occupancy ratio for the two components.
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spelling pubmed-29800272010-12-30 Bis(propan-2-yl) [(1S)-1-(4-fluoro­phen­yl)-1-hydr­oxy-2-nitro­ethyl]phospho­nate Mandal, Tanmay Samanta, Sampak Broker, Grant A. Zhao, Cong-Gui Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(21)FNO(6)P, a staggered conformation about the central P—C bond occurs, with the oxo and hydroxyl groups occupying diagonally opposite positions. The crystal structure features supra­molecular chains mediated by O—H⋯O hydrogen bonds, which propagate in the a-axis direction. A C—H⋯O inter­action consolidates the chains. Disorder was resolved for one of the isopropyl groups with a 0.60 (2):0.40 (2) occupancy ratio for the two components. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980027/ /pubmed/21580194 http://dx.doi.org/10.1107/S160053680905260X Text en © Mandal et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mandal, Tanmay
Samanta, Sampak
Broker, Grant A.
Zhao, Cong-Gui
Tiekink, Edward R. T.
Bis(propan-2-yl) [(1S)-1-(4-fluoro­phen­yl)-1-hydr­oxy-2-nitro­ethyl]phospho­nate
title Bis(propan-2-yl) [(1S)-1-(4-fluoro­phen­yl)-1-hydr­oxy-2-nitro­ethyl]phospho­nate
title_full Bis(propan-2-yl) [(1S)-1-(4-fluoro­phen­yl)-1-hydr­oxy-2-nitro­ethyl]phospho­nate
title_fullStr Bis(propan-2-yl) [(1S)-1-(4-fluoro­phen­yl)-1-hydr­oxy-2-nitro­ethyl]phospho­nate
title_full_unstemmed Bis(propan-2-yl) [(1S)-1-(4-fluoro­phen­yl)-1-hydr­oxy-2-nitro­ethyl]phospho­nate
title_short Bis(propan-2-yl) [(1S)-1-(4-fluoro­phen­yl)-1-hydr­oxy-2-nitro­ethyl]phospho­nate
title_sort bis(propan-2-yl) [(1s)-1-(4-fluoro­phen­yl)-1-hydr­oxy-2-nitro­ethyl]phospho­nate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980027/
https://www.ncbi.nlm.nih.gov/pubmed/21580194
http://dx.doi.org/10.1107/S160053680905260X
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AT brokergranta bispropan2yl1s14fluorophenyl1hydroxy2nitroethylphosphonate
AT zhaoconggui bispropan2yl1s14fluorophenyl1hydroxy2nitroethylphosphonate
AT tiekinkedwardrt bispropan2yl1s14fluorophenyl1hydroxy2nitroethylphosphonate

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