11-[3-(Dimethyl­amino)prop­yl]-6,11-dihydro­dibenzo[b,e]thiepin-11-ol

There are two independent mol­ecules (A and B) in the asymmetric unit of the title compound, C(19)H(23)NOS. In each mol­ecule, the seven-membered thiepine ring is bent into a slightly twisted V-shape. The dihedral angles between the mean planes of the two benzene rings fused to the thiepine ring are...

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Detalles Bibliográficos
Autores principales: Jasinski, Jerry P., Butcher, Ray J., Hakim Al-arique, Q. N. M., Yathirajan, H. S., Ramesha, A.R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980032/
https://www.ncbi.nlm.nih.gov/pubmed/21580050
http://dx.doi.org/10.1107/S1600536809053434
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author Jasinski, Jerry P.
Butcher, Ray J.
Hakim Al-arique, Q. N. M.
Yathirajan, H. S.
Ramesha, A.R.
author_facet Jasinski, Jerry P.
Butcher, Ray J.
Hakim Al-arique, Q. N. M.
Yathirajan, H. S.
Ramesha, A.R.
author_sort Jasinski, Jerry P.
collection PubMed
description There are two independent mol­ecules (A and B) in the asymmetric unit of the title compound, C(19)H(23)NOS. In each mol­ecule, the seven-membered thiepine ring is bent into a slightly twisted V-shape. The dihedral angles between the mean planes of the two benzene rings fused to the thiepine ring are 75.7 (5) in mol­ecule A and 73.8 (4)° in mol­ecule B. In both mol­ecules, an intra­molecular O—H⋯N hydrogen bond occurs. In the crystal, weak inter­molecular C—H⋯O and C—H⋯π-ring inter­actions are observed.
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spelling pubmed-29800322010-12-30 11-[3-(Dimethyl­amino)prop­yl]-6,11-dihydro­dibenzo[b,e]thiepin-11-ol Jasinski, Jerry P. Butcher, Ray J. Hakim Al-arique, Q. N. M. Yathirajan, H. S. Ramesha, A.R. Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent mol­ecules (A and B) in the asymmetric unit of the title compound, C(19)H(23)NOS. In each mol­ecule, the seven-membered thiepine ring is bent into a slightly twisted V-shape. The dihedral angles between the mean planes of the two benzene rings fused to the thiepine ring are 75.7 (5) in mol­ecule A and 73.8 (4)° in mol­ecule B. In both mol­ecules, an intra­molecular O—H⋯N hydrogen bond occurs. In the crystal, weak inter­molecular C—H⋯O and C—H⋯π-ring inter­actions are observed. International Union of Crystallography 2009-12-16 /pmc/articles/PMC2980032/ /pubmed/21580050 http://dx.doi.org/10.1107/S1600536809053434 Text en © Jasinski et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jasinski, Jerry P.
Butcher, Ray J.
Hakim Al-arique, Q. N. M.
Yathirajan, H. S.
Ramesha, A.R.
11-[3-(Dimethyl­amino)prop­yl]-6,11-dihydro­dibenzo[b,e]thiepin-11-ol
title 11-[3-(Dimethyl­amino)prop­yl]-6,11-dihydro­dibenzo[b,e]thiepin-11-ol
title_full 11-[3-(Dimethyl­amino)prop­yl]-6,11-dihydro­dibenzo[b,e]thiepin-11-ol
title_fullStr 11-[3-(Dimethyl­amino)prop­yl]-6,11-dihydro­dibenzo[b,e]thiepin-11-ol
title_full_unstemmed 11-[3-(Dimethyl­amino)prop­yl]-6,11-dihydro­dibenzo[b,e]thiepin-11-ol
title_short 11-[3-(Dimethyl­amino)prop­yl]-6,11-dihydro­dibenzo[b,e]thiepin-11-ol
title_sort 11-[3-(dimethyl­amino)prop­yl]-6,11-dihydro­dibenzo[b,e]thiepin-11-ol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980032/
https://www.ncbi.nlm.nih.gov/pubmed/21580050
http://dx.doi.org/10.1107/S1600536809053434
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AT rameshaar 113dimethylaminopropyl611dihydrodibenzobethiepin11ol

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