trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)

In the title compound, [Re(C(3)H(7)O)I(2)O(C(8)H(6)N(4))], the Re(V) atom adopts a distorted octa­hedral ReI(2)O(2)N(2) geometry, with the O atoms in a trans conformation and the I atoms in a cis conformation. Two intra­molecular C—H⋯I contacts occur. The crystal structure is stabilized by inter­mol...

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Detalles Bibliográficos
Autor principal: Kochel, Andrzej
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980033/
https://www.ncbi.nlm.nih.gov/pubmed/21579941
http://dx.doi.org/10.1107/S1600536809052556
Descripción
Sumario:In the title compound, [Re(C(3)H(7)O)I(2)O(C(8)H(6)N(4))], the Re(V) atom adopts a distorted octa­hedral ReI(2)O(2)N(2) geometry, with the O atoms in a trans conformation and the I atoms in a cis conformation. Two intra­molecular C—H⋯I contacts occur. The crystal structure is stabilized by inter­molecular C—H⋯O, C—H⋯N and C—H⋯I hydrogen bonds.

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