trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)

In the title compound, [Re(C(3)H(7)O)I(2)O(C(8)H(6)N(4))], the Re(V) atom adopts a distorted octa­hedral ReI(2)O(2)N(2) geometry, with the O atoms in a trans conformation and the I atoms in a cis conformation. Two intra­molecular C—H⋯I contacts occur. The crystal structure is stabilized by inter­mol...

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Detalles Bibliográficos
Autor principal: Kochel, Andrzej
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980033/
https://www.ncbi.nlm.nih.gov/pubmed/21579941
http://dx.doi.org/10.1107/S1600536809052556
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author Kochel, Andrzej
author_facet Kochel, Andrzej
author_sort Kochel, Andrzej
collection PubMed
description In the title compound, [Re(C(3)H(7)O)I(2)O(C(8)H(6)N(4))], the Re(V) atom adopts a distorted octa­hedral ReI(2)O(2)N(2) geometry, with the O atoms in a trans conformation and the I atoms in a cis conformation. Two intra­molecular C—H⋯I contacts occur. The crystal structure is stabilized by inter­molecular C—H⋯O, C—H⋯N and C—H⋯I hydrogen bonds.
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spelling pubmed-29800332010-12-30 trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V) Kochel, Andrzej Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Re(C(3)H(7)O)I(2)O(C(8)H(6)N(4))], the Re(V) atom adopts a distorted octa­hedral ReI(2)O(2)N(2) geometry, with the O atoms in a trans conformation and the I atoms in a cis conformation. Two intra­molecular C—H⋯I contacts occur. The crystal structure is stabilized by inter­molecular C—H⋯O, C—H⋯N and C—H⋯I hydrogen bonds. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980033/ /pubmed/21579941 http://dx.doi.org/10.1107/S1600536809052556 Text en © Andrzej Kochel 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kochel, Andrzej
trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)
title trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)
title_full trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)
title_fullStr trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)
title_full_unstemmed trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)
title_short trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)
title_sort trans-(2,2′-bipyrimidine)diiodido(isopropoxido)oxidorhenium(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980033/
https://www.ncbi.nlm.nih.gov/pubmed/21579941
http://dx.doi.org/10.1107/S1600536809052556
work_keys_str_mv AT kochelandrzej trans22bipyrimidinediiodidoisopropoxidooxidorheniumv

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