Cargando…
catena-Poly[[diaquadichloridomanganese(II)]-μ-1,1′-bis(1H-1,2,4-triazol-1-ylmethyl)ferrocene]
In the title complex, [FeMn(C(8)H(8)N(3))(2)Cl(2)(H(2)O)(2)](n), the Mn(II) atom, located on an inversion center, is octahedrally coordinated by two N atoms from two adjacent 1,1′-bis(1H-1,2,4-triazol-1-ylmethyl)ferrocene (btmf) ligands and two Cl atoms forming the equatorial plane, with the axia...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980034/ https://www.ncbi.nlm.nih.gov/pubmed/21579985 http://dx.doi.org/10.1107/S1600536809053823 |
Sumario: | In the title complex, [FeMn(C(8)H(8)N(3))(2)Cl(2)(H(2)O)(2)](n), the Mn(II) atom, located on an inversion center, is octahedrally coordinated by two N atoms from two adjacent 1,1′-bis(1H-1,2,4-triazol-1-ylmethyl)ferrocene (btmf) ligands and two Cl atoms forming the equatorial plane, with the axial positions occupied by two O atoms of coordinated water molecules. The btmf ligands link adjoining Mn(II) atoms into a zigzag chain along the a axis. The crystal structure is stabilized by intermolecular O—H⋯N hydrogen bonds, which link the chains, forming a two-dimensional layer parallel to (10[Image: see text]); O—H⋯Cl interactions link the layers, forming a three-dimensional network. |
---|