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catena-Poly[[diaqua­dichlorido­manganese(II)]-μ-1,1′-bis­(1H-1,2,4-triazol-1-ylmeth­yl)ferrocene]

In the title complex, [FeMn(C(8)H(8)N(3))(2)Cl(2)(H(2)O)(2)](n), the Mn(II) atom, located on an inversion center, is octa­hedrally coordinated by two N atoms from two adjacent 1,1′-bis­(1H-1,2,4-triazol-1-ylmeth­yl)ferrocene (btmf) ligands and two Cl atoms forming the equatorial plane, with the axia...

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Detalles Bibliográficos
Autores principales: Shi, Chong-Yu, Zhou, Xiao-Li, Wu, Bo, Zhu, Ni, Weia, Zhen-Shu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980034/
https://www.ncbi.nlm.nih.gov/pubmed/21579985
http://dx.doi.org/10.1107/S1600536809053823
Descripción
Sumario:In the title complex, [FeMn(C(8)H(8)N(3))(2)Cl(2)(H(2)O)(2)](n), the Mn(II) atom, located on an inversion center, is octa­hedrally coordinated by two N atoms from two adjacent 1,1′-bis­(1H-1,2,4-triazol-1-ylmeth­yl)ferrocene (btmf) ligands and two Cl atoms forming the equatorial plane, with the axial positions occupied by two O atoms of coordinated water mol­ecules. The btmf ligands link adjoining Mn(II) atoms into a zigzag chain along the a axis. The crystal structure is stabilized by inter­molecular O—H⋯N hydrogen bonds, which link the chains, forming a two-dimensional layer parallel to (10[Image: see text]); O—H⋯Cl inter­actions link the layers, forming a three-dimensional network.