Cargando…
catena-Poly[[diaquadichloridomanganese(II)]-μ-1,1′-bis(1H-1,2,4-triazol-1-ylmethyl)ferrocene]
In the title complex, [FeMn(C(8)H(8)N(3))(2)Cl(2)(H(2)O)(2)](n), the Mn(II) atom, located on an inversion center, is octahedrally coordinated by two N atoms from two adjacent 1,1′-bis(1H-1,2,4-triazol-1-ylmethyl)ferrocene (btmf) ligands and two Cl atoms forming the equatorial plane, with the axia...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980034/ https://www.ncbi.nlm.nih.gov/pubmed/21579985 http://dx.doi.org/10.1107/S1600536809053823 |
_version_ | 1782191561668296704 |
---|---|
author | Shi, Chong-Yu Zhou, Xiao-Li Wu, Bo Zhu, Ni Weia, Zhen-Shu |
author_facet | Shi, Chong-Yu Zhou, Xiao-Li Wu, Bo Zhu, Ni Weia, Zhen-Shu |
author_sort | Shi, Chong-Yu |
collection | PubMed |
description | In the title complex, [FeMn(C(8)H(8)N(3))(2)Cl(2)(H(2)O)(2)](n), the Mn(II) atom, located on an inversion center, is octahedrally coordinated by two N atoms from two adjacent 1,1′-bis(1H-1,2,4-triazol-1-ylmethyl)ferrocene (btmf) ligands and two Cl atoms forming the equatorial plane, with the axial positions occupied by two O atoms of coordinated water molecules. The btmf ligands link adjoining Mn(II) atoms into a zigzag chain along the a axis. The crystal structure is stabilized by intermolecular O—H⋯N hydrogen bonds, which link the chains, forming a two-dimensional layer parallel to (10[Image: see text]); O—H⋯Cl interactions link the layers, forming a three-dimensional network. |
format | Text |
id | pubmed-2980034 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29800342010-12-30 catena-Poly[[diaquadichloridomanganese(II)]-μ-1,1′-bis(1H-1,2,4-triazol-1-ylmethyl)ferrocene] Shi, Chong-Yu Zhou, Xiao-Li Wu, Bo Zhu, Ni Weia, Zhen-Shu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [FeMn(C(8)H(8)N(3))(2)Cl(2)(H(2)O)(2)](n), the Mn(II) atom, located on an inversion center, is octahedrally coordinated by two N atoms from two adjacent 1,1′-bis(1H-1,2,4-triazol-1-ylmethyl)ferrocene (btmf) ligands and two Cl atoms forming the equatorial plane, with the axial positions occupied by two O atoms of coordinated water molecules. The btmf ligands link adjoining Mn(II) atoms into a zigzag chain along the a axis. The crystal structure is stabilized by intermolecular O—H⋯N hydrogen bonds, which link the chains, forming a two-dimensional layer parallel to (10[Image: see text]); O—H⋯Cl interactions link the layers, forming a three-dimensional network. International Union of Crystallography 2009-12-24 /pmc/articles/PMC2980034/ /pubmed/21579985 http://dx.doi.org/10.1107/S1600536809053823 Text en © Shi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shi, Chong-Yu Zhou, Xiao-Li Wu, Bo Zhu, Ni Weia, Zhen-Shu catena-Poly[[diaquadichloridomanganese(II)]-μ-1,1′-bis(1H-1,2,4-triazol-1-ylmethyl)ferrocene] |
title |
catena-Poly[[diaquadichloridomanganese(II)]-μ-1,1′-bis(1H-1,2,4-triazol-1-ylmethyl)ferrocene] |
title_full |
catena-Poly[[diaquadichloridomanganese(II)]-μ-1,1′-bis(1H-1,2,4-triazol-1-ylmethyl)ferrocene] |
title_fullStr |
catena-Poly[[diaquadichloridomanganese(II)]-μ-1,1′-bis(1H-1,2,4-triazol-1-ylmethyl)ferrocene] |
title_full_unstemmed |
catena-Poly[[diaquadichloridomanganese(II)]-μ-1,1′-bis(1H-1,2,4-triazol-1-ylmethyl)ferrocene] |
title_short |
catena-Poly[[diaquadichloridomanganese(II)]-μ-1,1′-bis(1H-1,2,4-triazol-1-ylmethyl)ferrocene] |
title_sort | catena-poly[[diaquadichloridomanganese(ii)]-μ-1,1′-bis(1h-1,2,4-triazol-1-ylmethyl)ferrocene] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980034/ https://www.ncbi.nlm.nih.gov/pubmed/21579985 http://dx.doi.org/10.1107/S1600536809053823 |
work_keys_str_mv | AT shichongyu catenapolydiaquadichloridomanganeseiim11bis1h124triazol1ylmethylferrocene AT zhouxiaoli catenapolydiaquadichloridomanganeseiim11bis1h124triazol1ylmethylferrocene AT wubo catenapolydiaquadichloridomanganeseiim11bis1h124triazol1ylmethylferrocene AT zhuni catenapolydiaquadichloridomanganeseiim11bis1h124triazol1ylmethylferrocene AT weiazhenshu catenapolydiaquadichloridomanganeseiim11bis1h124triazol1ylmethylferrocene |