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catena-Poly[[diaqua­dichlorido­manganese(II)]-μ-1,1′-bis­(1H-1,2,4-triazol-1-ylmeth­yl)ferrocene]

In the title complex, [FeMn(C(8)H(8)N(3))(2)Cl(2)(H(2)O)(2)](n), the Mn(II) atom, located on an inversion center, is octa­hedrally coordinated by two N atoms from two adjacent 1,1′-bis­(1H-1,2,4-triazol-1-ylmeth­yl)ferrocene (btmf) ligands and two Cl atoms forming the equatorial plane, with the axia...

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Detalles Bibliográficos
Autores principales: Shi, Chong-Yu, Zhou, Xiao-Li, Wu, Bo, Zhu, Ni, Weia, Zhen-Shu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980034/
https://www.ncbi.nlm.nih.gov/pubmed/21579985
http://dx.doi.org/10.1107/S1600536809053823
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author Shi, Chong-Yu
Zhou, Xiao-Li
Wu, Bo
Zhu, Ni
Weia, Zhen-Shu
author_facet Shi, Chong-Yu
Zhou, Xiao-Li
Wu, Bo
Zhu, Ni
Weia, Zhen-Shu
author_sort Shi, Chong-Yu
collection PubMed
description In the title complex, [FeMn(C(8)H(8)N(3))(2)Cl(2)(H(2)O)(2)](n), the Mn(II) atom, located on an inversion center, is octa­hedrally coordinated by two N atoms from two adjacent 1,1′-bis­(1H-1,2,4-triazol-1-ylmeth­yl)ferrocene (btmf) ligands and two Cl atoms forming the equatorial plane, with the axial positions occupied by two O atoms of coordinated water mol­ecules. The btmf ligands link adjoining Mn(II) atoms into a zigzag chain along the a axis. The crystal structure is stabilized by inter­molecular O—H⋯N hydrogen bonds, which link the chains, forming a two-dimensional layer parallel to (10[Image: see text]); O—H⋯Cl inter­actions link the layers, forming a three-dimensional network.
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spelling pubmed-29800342010-12-30 catena-Poly[[diaqua­dichlorido­manganese(II)]-μ-1,1′-bis­(1H-1,2,4-triazol-1-ylmeth­yl)ferrocene] Shi, Chong-Yu Zhou, Xiao-Li Wu, Bo Zhu, Ni Weia, Zhen-Shu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [FeMn(C(8)H(8)N(3))(2)Cl(2)(H(2)O)(2)](n), the Mn(II) atom, located on an inversion center, is octa­hedrally coordinated by two N atoms from two adjacent 1,1′-bis­(1H-1,2,4-triazol-1-ylmeth­yl)ferrocene (btmf) ligands and two Cl atoms forming the equatorial plane, with the axial positions occupied by two O atoms of coordinated water mol­ecules. The btmf ligands link adjoining Mn(II) atoms into a zigzag chain along the a axis. The crystal structure is stabilized by inter­molecular O—H⋯N hydrogen bonds, which link the chains, forming a two-dimensional layer parallel to (10[Image: see text]); O—H⋯Cl inter­actions link the layers, forming a three-dimensional network. International Union of Crystallography 2009-12-24 /pmc/articles/PMC2980034/ /pubmed/21579985 http://dx.doi.org/10.1107/S1600536809053823 Text en © Shi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Chong-Yu
Zhou, Xiao-Li
Wu, Bo
Zhu, Ni
Weia, Zhen-Shu
catena-Poly[[diaqua­dichlorido­manganese(II)]-μ-1,1′-bis­(1H-1,2,4-triazol-1-ylmeth­yl)ferrocene]
title catena-Poly[[diaqua­dichlorido­manganese(II)]-μ-1,1′-bis­(1H-1,2,4-triazol-1-ylmeth­yl)ferrocene]
title_full catena-Poly[[diaqua­dichlorido­manganese(II)]-μ-1,1′-bis­(1H-1,2,4-triazol-1-ylmeth­yl)ferrocene]
title_fullStr catena-Poly[[diaqua­dichlorido­manganese(II)]-μ-1,1′-bis­(1H-1,2,4-triazol-1-ylmeth­yl)ferrocene]
title_full_unstemmed catena-Poly[[diaqua­dichlorido­manganese(II)]-μ-1,1′-bis­(1H-1,2,4-triazol-1-ylmeth­yl)ferrocene]
title_short catena-Poly[[diaqua­dichlorido­manganese(II)]-μ-1,1′-bis­(1H-1,2,4-triazol-1-ylmeth­yl)ferrocene]
title_sort catena-poly[[diaqua­dichlorido­manganese(ii)]-μ-1,1′-bis­(1h-1,2,4-triazol-1-ylmeth­yl)ferrocene]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980034/
https://www.ncbi.nlm.nih.gov/pubmed/21579985
http://dx.doi.org/10.1107/S1600536809053823
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