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[μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methyl­phen­yl)­phosphine-3κP]-triangulo-triruthenium(0)

In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(21)H(21)P)(CO)(9)], the bis­(diphenyl­arsino)methane ligand bridges a Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(3) tri...

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Autores principales: Shawkataly, Omar bin, Khan, Imthyaz Ahmed, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980046/
https://www.ncbi.nlm.nih.gov/pubmed/21579935
http://dx.doi.org/10.1107/S1600536809049940
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author Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Shawkataly, Omar bin
collection PubMed
description In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(21)H(21)P)(CO)(9)], the bis­(diphenyl­arsino)methane ligand bridges a Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phenyl rings of the phosphine make dihedral angles of 86.89 (19), 82.1 (2) and 63.0 (2)° with each other. The dihedral angles between the two phenyl rings are 73.8 (2) and 82.2 (3)° for the two diphenyl­arsino groups. An intra­molecular C—H⋯O hydrogen bond stabilizes the mol­ecular structure. In the crystal packing, mol­ecules are linked into chains down the b axis via inter­molecular C—H⋯O hydrogen bonds.
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spelling pubmed-29800462010-12-30 [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methyl­phen­yl)­phosphine-3κP]-triangulo-triruthenium(0) Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(21)H(21)P)(CO)(9)], the bis­(diphenyl­arsino)methane ligand bridges a Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phenyl rings of the phosphine make dihedral angles of 86.89 (19), 82.1 (2) and 63.0 (2)° with each other. The dihedral angles between the two phenyl rings are 73.8 (2) and 82.2 (3)° for the two diphenyl­arsino groups. An intra­molecular C—H⋯O hydrogen bond stabilizes the mol­ecular structure. In the crystal packing, mol­ecules are linked into chains down the b axis via inter­molecular C—H⋯O hydrogen bonds. International Union of Crystallography 2009-12-09 /pmc/articles/PMC2980046/ /pubmed/21579935 http://dx.doi.org/10.1107/S1600536809049940 Text en © Shawkataly et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Yeap, Chin Sing
Fun, Hoong-Kun
[μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methyl­phen­yl)­phosphine-3κP]-triangulo-triruthenium(0)
title [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methyl­phen­yl)­phosphine-3κP]-triangulo-triruthenium(0)
title_full [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methyl­phen­yl)­phosphine-3κP]-triangulo-triruthenium(0)
title_fullStr [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methyl­phen­yl)­phosphine-3κP]-triangulo-triruthenium(0)
title_full_unstemmed [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methyl­phen­yl)­phosphine-3κP]-triangulo-triruthenium(0)
title_short [μ-Bis(diphenyl­arsino)methane-1:2κ(2) As:As′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-methyl­phen­yl)­phosphine-3κP]-triangulo-triruthenium(0)
title_sort [μ-bis(diphenyl­arsino)methane-1:2κ(2) as:as′]nona­carbonyl-1κ(3) c,2κ(3) c,3κ(3) c-[tris­(4-methyl­phen­yl)­phosphine-3κp]-triangulo-triruthenium(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980046/
https://www.ncbi.nlm.nih.gov/pubmed/21579935
http://dx.doi.org/10.1107/S1600536809049940
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