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[μ-Bis(diphenylarsino)methane-1:2κ(2) As:As′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0)
In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(21)H(21)P)(CO)(9)], the bis(diphenylarsino)methane ligand bridges a Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(3) tri...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980046/ https://www.ncbi.nlm.nih.gov/pubmed/21579935 http://dx.doi.org/10.1107/S1600536809049940 |
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author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun |
author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun |
author_sort | Shawkataly, Omar bin |
collection | PubMed |
description | In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(21)H(21)P)(CO)(9)], the bis(diphenylarsino)methane ligand bridges a Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phenyl rings of the phosphine make dihedral angles of 86.89 (19), 82.1 (2) and 63.0 (2)° with each other. The dihedral angles between the two phenyl rings are 73.8 (2) and 82.2 (3)° for the two diphenylarsino groups. An intramolecular C—H⋯O hydrogen bond stabilizes the molecular structure. In the crystal packing, molecules are linked into chains down the b axis via intermolecular C—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2980046 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29800462010-12-30 [μ-Bis(diphenylarsino)methane-1:2κ(2) As:As′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0) Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(21)H(21)P)(CO)(9)], the bis(diphenylarsino)methane ligand bridges a Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phenyl rings of the phosphine make dihedral angles of 86.89 (19), 82.1 (2) and 63.0 (2)° with each other. The dihedral angles between the two phenyl rings are 73.8 (2) and 82.2 (3)° for the two diphenylarsino groups. An intramolecular C—H⋯O hydrogen bond stabilizes the molecular structure. In the crystal packing, molecules are linked into chains down the b axis via intermolecular C—H⋯O hydrogen bonds. International Union of Crystallography 2009-12-09 /pmc/articles/PMC2980046/ /pubmed/21579935 http://dx.doi.org/10.1107/S1600536809049940 Text en © Shawkataly et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun [μ-Bis(diphenylarsino)methane-1:2κ(2) As:As′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0) |
title | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0) |
title_full | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0) |
title_fullStr | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0) |
title_full_unstemmed | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0) |
title_short | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0) |
title_sort | [μ-bis(diphenylarsino)methane-1:2κ(2)
as:as′]nonacarbonyl-1κ(3)
c,2κ(3)
c,3κ(3)
c-[tris(4-methylphenyl)phosphine-3κp]-triangulo-triruthenium(0) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980046/ https://www.ncbi.nlm.nih.gov/pubmed/21579935 http://dx.doi.org/10.1107/S1600536809049940 |
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