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Diaqua-1κO,2κO-(2,2′-bi-1H-imidazole-1κ(2) N (3),N (3′))(oxalato-2κ(2) O (1),O (2))di-μ-oxido-κ(4) O:O-dioxido-1κO,2κO-dimolybdenum(V) trihydrate
In the title compound, [Mo(2)(C(2)O(4))O(4)(C(6)H(6)N(4))(H(2)O)(2)]·3H(2)O, the coordination polyhedra for both Mo(V) atoms consist of two bridging O atoms, two atoms of the chelating ligand (oxalate or diimidazole), a terminal O atom and one H(2)O molecule. The two distorted octahedrally coordin...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980048/ https://www.ncbi.nlm.nih.gov/pubmed/21579926 http://dx.doi.org/10.1107/S1600536809052003 |
| _version_ | 1782191564948242432 |
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| author | Zhang, Xiutang Wei, Peihai Shi, Congwen Li, Bin Hu, Bo |
| author_facet | Zhang, Xiutang Wei, Peihai Shi, Congwen Li, Bin Hu, Bo |
| author_sort | Zhang, Xiutang |
| collection | PubMed |
| description | In the title compound, [Mo(2)(C(2)O(4))O(4)(C(6)H(6)N(4))(H(2)O)(2)]·3H(2)O, the coordination polyhedra for both Mo(V) atoms consist of two bridging O atoms, two atoms of the chelating ligand (oxalate or diimidazole), a terminal O atom and one H(2)O molecule. The two distorted octahedrally coordinated Mo(V) atoms are linked together via O—O edge-sharing and Mo—Mo interactions with a Mo—Mo bond length of 2.564 (5) Å. Uncoordinated water molecules are situated in the voids of the crystal structure. N—H⋯O and O—H⋯O hydrogen bonding between the neutral molecules and the water molecules lead to a consolidation of the structure. |
| format | Text |
| id | pubmed-2980048 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29800482010-12-30 Diaqua-1κO,2κO-(2,2′-bi-1H-imidazole-1κ(2) N (3),N (3′))(oxalato-2κ(2) O (1),O (2))di-μ-oxido-κ(4) O:O-dioxido-1κO,2κO-dimolybdenum(V) trihydrate Zhang, Xiutang Wei, Peihai Shi, Congwen Li, Bin Hu, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mo(2)(C(2)O(4))O(4)(C(6)H(6)N(4))(H(2)O)(2)]·3H(2)O, the coordination polyhedra for both Mo(V) atoms consist of two bridging O atoms, two atoms of the chelating ligand (oxalate or diimidazole), a terminal O atom and one H(2)O molecule. The two distorted octahedrally coordinated Mo(V) atoms are linked together via O—O edge-sharing and Mo—Mo interactions with a Mo—Mo bond length of 2.564 (5) Å. Uncoordinated water molecules are situated in the voids of the crystal structure. N—H⋯O and O—H⋯O hydrogen bonding between the neutral molecules and the water molecules lead to a consolidation of the structure. International Union of Crystallography 2009-12-09 /pmc/articles/PMC2980048/ /pubmed/21579926 http://dx.doi.org/10.1107/S1600536809052003 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Xiutang Wei, Peihai Shi, Congwen Li, Bin Hu, Bo Diaqua-1κO,2κO-(2,2′-bi-1H-imidazole-1κ(2) N (3),N (3′))(oxalato-2κ(2) O (1),O (2))di-μ-oxido-κ(4) O:O-dioxido-1κO,2κO-dimolybdenum(V) trihydrate |
| title | Diaqua-1κO,2κO-(2,2′-bi-1H-imidazole-1κ(2)
N
(3),N
(3′))(oxalato-2κ(2)
O
(1),O
(2))di-μ-oxido-κ(4)
O:O-dioxido-1κO,2κO-dimolybdenum(V) trihydrate |
| title_full | Diaqua-1κO,2κO-(2,2′-bi-1H-imidazole-1κ(2)
N
(3),N
(3′))(oxalato-2κ(2)
O
(1),O
(2))di-μ-oxido-κ(4)
O:O-dioxido-1κO,2κO-dimolybdenum(V) trihydrate |
| title_fullStr | Diaqua-1κO,2κO-(2,2′-bi-1H-imidazole-1κ(2)
N
(3),N
(3′))(oxalato-2κ(2)
O
(1),O
(2))di-μ-oxido-κ(4)
O:O-dioxido-1κO,2κO-dimolybdenum(V) trihydrate |
| title_full_unstemmed | Diaqua-1κO,2κO-(2,2′-bi-1H-imidazole-1κ(2)
N
(3),N
(3′))(oxalato-2κ(2)
O
(1),O
(2))di-μ-oxido-κ(4)
O:O-dioxido-1κO,2κO-dimolybdenum(V) trihydrate |
| title_short | Diaqua-1κO,2κO-(2,2′-bi-1H-imidazole-1κ(2)
N
(3),N
(3′))(oxalato-2κ(2)
O
(1),O
(2))di-μ-oxido-κ(4)
O:O-dioxido-1κO,2κO-dimolybdenum(V) trihydrate |
| title_sort | diaqua-1κo,2κo-(2,2′-bi-1h-imidazole-1κ(2)
n
(3),n
(3′))(oxalato-2κ(2)
o
(1),o
(2))di-μ-oxido-κ(4)
o:o-dioxido-1κo,2κo-dimolybdenum(v) trihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980048/ https://www.ncbi.nlm.nih.gov/pubmed/21579926 http://dx.doi.org/10.1107/S1600536809052003 |
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