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Bromido[(1,2,5,6-η)-cycloocta-1,5-diene]methylplatinum(II)
In the title complex, [PtBr(CH(3))(C(8)H(12))], the Pt(II) ion is in a distorted square-planar environment defined by the Br and methyl C atoms and the mid-points of the two π-coordinated double bonds of cycloocta-1,5-diene. As a result of the different trans influences of the Br atom and the methy...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980049/ https://www.ncbi.nlm.nih.gov/pubmed/21579945 http://dx.doi.org/10.1107/S1600536809052660 |
| _version_ | 1782191565226115072 |
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| author | Ha, Kwang |
| author_facet | Ha, Kwang |
| author_sort | Ha, Kwang |
| collection | PubMed |
| description | In the title complex, [PtBr(CH(3))(C(8)H(12))], the Pt(II) ion is in a distorted square-planar environment defined by the Br and methyl C atoms and the mid-points of the two π-coordinated double bonds of cycloocta-1,5-diene. As a result of the different trans influences of the Br atom and the methyl group, the Pt—C bonds trans to the methyl group [2.262 (11) and 2.261 (10) Å] are longer than those trans to the Br atom [2.118 (8) and 2.138 (9) Å]. |
| format | Text |
| id | pubmed-2980049 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29800492010-12-30 Bromido[(1,2,5,6-η)-cycloocta-1,5-diene]methylplatinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PtBr(CH(3))(C(8)H(12))], the Pt(II) ion is in a distorted square-planar environment defined by the Br and methyl C atoms and the mid-points of the two π-coordinated double bonds of cycloocta-1,5-diene. As a result of the different trans influences of the Br atom and the methyl group, the Pt—C bonds trans to the methyl group [2.262 (11) and 2.261 (10) Å] are longer than those trans to the Br atom [2.118 (8) and 2.138 (9) Å]. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980049/ /pubmed/21579945 http://dx.doi.org/10.1107/S1600536809052660 Text en © Kwang Ha 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ha, Kwang Bromido[(1,2,5,6-η)-cycloocta-1,5-diene]methylplatinum(II) |
| title | Bromido[(1,2,5,6-η)-cycloocta-1,5-diene]methylplatinum(II) |
| title_full | Bromido[(1,2,5,6-η)-cycloocta-1,5-diene]methylplatinum(II) |
| title_fullStr | Bromido[(1,2,5,6-η)-cycloocta-1,5-diene]methylplatinum(II) |
| title_full_unstemmed | Bromido[(1,2,5,6-η)-cycloocta-1,5-diene]methylplatinum(II) |
| title_short | Bromido[(1,2,5,6-η)-cycloocta-1,5-diene]methylplatinum(II) |
| title_sort | bromido[(1,2,5,6-η)-cycloocta-1,5-diene]methylplatinum(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980049/ https://www.ncbi.nlm.nih.gov/pubmed/21579945 http://dx.doi.org/10.1107/S1600536809052660 |
| work_keys_str_mv | AT hakwang bromido1256ēcycloocta15dienemethylplatinumii |