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mer-Bis[3,5-difluoro-2-(2-pyridyl)phenyl-κ(2) C (1),N]{5-(2-pyridyl-κN)-3-[3-(4-vinylbenzyloxy)phenyl]-1,2,4-triazol-1-ido}iridium(III) methanol solvate
In the title compound, [Ir(C(11)H(6)F(2)N)(2)(C(22)H(17)N(4)O)]·CH(3)OH, the coordination at iridium is essentially octahedral, but with distortions associated with the bite angles of the ligands [76.25 (9)–80.71 (12)°] and the differing trans influences of C and N ligands [Ir—N = 2.04 Å (average)...
| Autores principales: | , , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980050/ https://www.ncbi.nlm.nih.gov/pubmed/21579961 http://dx.doi.org/10.1107/S1600536809052726 |
| _version_ | 1782191565457850368 |
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| author | Jones, Peter G. Debeaux, Marc Weinkauf, Andreas Hopf, Henning Kowalsky, Wolfgang Johannes, Hans-Hermann |
| author_facet | Jones, Peter G. Debeaux, Marc Weinkauf, Andreas Hopf, Henning Kowalsky, Wolfgang Johannes, Hans-Hermann |
| author_sort | Jones, Peter G. |
| collection | PubMed |
| description | In the title compound, [Ir(C(11)H(6)F(2)N)(2)(C(22)H(17)N(4)O)]·CH(3)OH, the coordination at iridium is essentially octahedral, but with distortions associated with the bite angles of the ligands [76.25 (9)–80.71 (12)°] and the differing trans influences of C and N ligands [Ir—N = 2.04 Å (average) trans to N but 2.14 Å trans to C]. All three bidentate ligands have coordinating ring systems that are almost coplanar [interplanar angles = 1.7 (1)–3.8 (2)°]. The vinylbenzyl group is disordered over two positions with occupations of 0.653 (4) and 0.347 (4). The methanol solvent molecule is involved in a classical O—H⋯N hydrogen bond to a triazole N atom. |
| format | Text |
| id | pubmed-2980050 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29800502010-12-30 mer-Bis[3,5-difluoro-2-(2-pyridyl)phenyl-κ(2) C (1),N]{5-(2-pyridyl-κN)-3-[3-(4-vinylbenzyloxy)phenyl]-1,2,4-triazol-1-ido}iridium(III) methanol solvate Jones, Peter G. Debeaux, Marc Weinkauf, Andreas Hopf, Henning Kowalsky, Wolfgang Johannes, Hans-Hermann Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ir(C(11)H(6)F(2)N)(2)(C(22)H(17)N(4)O)]·CH(3)OH, the coordination at iridium is essentially octahedral, but with distortions associated with the bite angles of the ligands [76.25 (9)–80.71 (12)°] and the differing trans influences of C and N ligands [Ir—N = 2.04 Å (average) trans to N but 2.14 Å trans to C]. All three bidentate ligands have coordinating ring systems that are almost coplanar [interplanar angles = 1.7 (1)–3.8 (2)°]. The vinylbenzyl group is disordered over two positions with occupations of 0.653 (4) and 0.347 (4). The methanol solvent molecule is involved in a classical O—H⋯N hydrogen bond to a triazole N atom. International Union of Crystallography 2009-12-16 /pmc/articles/PMC2980050/ /pubmed/21579961 http://dx.doi.org/10.1107/S1600536809052726 Text en © Jones et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Jones, Peter G. Debeaux, Marc Weinkauf, Andreas Hopf, Henning Kowalsky, Wolfgang Johannes, Hans-Hermann mer-Bis[3,5-difluoro-2-(2-pyridyl)phenyl-κ(2) C (1),N]{5-(2-pyridyl-κN)-3-[3-(4-vinylbenzyloxy)phenyl]-1,2,4-triazol-1-ido}iridium(III) methanol solvate |
| title |
mer-Bis[3,5-difluoro-2-(2-pyridyl)phenyl-κ(2)
C
(1),N]{5-(2-pyridyl-κN)-3-[3-(4-vinylbenzyloxy)phenyl]-1,2,4-triazol-1-ido}iridium(III) methanol solvate |
| title_full |
mer-Bis[3,5-difluoro-2-(2-pyridyl)phenyl-κ(2)
C
(1),N]{5-(2-pyridyl-κN)-3-[3-(4-vinylbenzyloxy)phenyl]-1,2,4-triazol-1-ido}iridium(III) methanol solvate |
| title_fullStr |
mer-Bis[3,5-difluoro-2-(2-pyridyl)phenyl-κ(2)
C
(1),N]{5-(2-pyridyl-κN)-3-[3-(4-vinylbenzyloxy)phenyl]-1,2,4-triazol-1-ido}iridium(III) methanol solvate |
| title_full_unstemmed |
mer-Bis[3,5-difluoro-2-(2-pyridyl)phenyl-κ(2)
C
(1),N]{5-(2-pyridyl-κN)-3-[3-(4-vinylbenzyloxy)phenyl]-1,2,4-triazol-1-ido}iridium(III) methanol solvate |
| title_short |
mer-Bis[3,5-difluoro-2-(2-pyridyl)phenyl-κ(2)
C
(1),N]{5-(2-pyridyl-κN)-3-[3-(4-vinylbenzyloxy)phenyl]-1,2,4-triazol-1-ido}iridium(III) methanol solvate |
| title_sort | mer-bis[3,5-difluoro-2-(2-pyridyl)phenyl-κ(2)
c
(1),n]{5-(2-pyridyl-κn)-3-[3-(4-vinylbenzyloxy)phenyl]-1,2,4-triazol-1-ido}iridium(iii) methanol solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980050/ https://www.ncbi.nlm.nih.gov/pubmed/21579961 http://dx.doi.org/10.1107/S1600536809052726 |
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