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Bis(N-triisopropyl­silyl­quinolin-8-aminato)nickel(II)

The reddish-brown title complex, [Ni(C(18)H(27)N(2)Si)(2)], was prepared via the salt-metathesis reaction of N-triisopropyl­silyl-8-amido­quinoline lithium with nickelocene (NiCp(2)). The asymmetric unit contains two symmetry-independent mol­ecules with the Ni atoms in distorted tetra­hedral environ...

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Detalles Bibliográficos
Autores principales: Malassa, Astrid, Jäger, Benjamin, Görls, Helmar, Westerhausen, Matthias
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980055/
https://www.ncbi.nlm.nih.gov/pubmed/21579956
http://dx.doi.org/10.1107/S1600536809051708
Descripción
Sumario:The reddish-brown title complex, [Ni(C(18)H(27)N(2)Si)(2)], was prepared via the salt-metathesis reaction of N-triisopropyl­silyl-8-amido­quinoline lithium with nickelocene (NiCp(2)). The asymmetric unit contains two symmetry-independent mol­ecules with the Ni atoms in distorted tetra­hedral environments.