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Bis(N-triisopropyl­silyl­quinolin-8-aminato)nickel(II)

The reddish-brown title complex, [Ni(C(18)H(27)N(2)Si)(2)], was prepared via the salt-metathesis reaction of N-triisopropyl­silyl-8-amido­quinoline lithium with nickelocene (NiCp(2)). The asymmetric unit contains two symmetry-independent mol­ecules with the Ni atoms in distorted tetra­hedral environ...

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Detalles Bibliográficos
Autores principales: Malassa, Astrid, Jäger, Benjamin, Görls, Helmar, Westerhausen, Matthias
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980055/
https://www.ncbi.nlm.nih.gov/pubmed/21579956
http://dx.doi.org/10.1107/S1600536809051708
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author Malassa, Astrid
Jäger, Benjamin
Görls, Helmar
Westerhausen, Matthias
author_facet Malassa, Astrid
Jäger, Benjamin
Görls, Helmar
Westerhausen, Matthias
author_sort Malassa, Astrid
collection PubMed
description The reddish-brown title complex, [Ni(C(18)H(27)N(2)Si)(2)], was prepared via the salt-metathesis reaction of N-triisopropyl­silyl-8-amido­quinoline lithium with nickelocene (NiCp(2)). The asymmetric unit contains two symmetry-independent mol­ecules with the Ni atoms in distorted tetra­hedral environments.
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spelling pubmed-29800552010-12-30 Bis(N-triisopropyl­silyl­quinolin-8-aminato)nickel(II) Malassa, Astrid Jäger, Benjamin Görls, Helmar Westerhausen, Matthias Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reddish-brown title complex, [Ni(C(18)H(27)N(2)Si)(2)], was prepared via the salt-metathesis reaction of N-triisopropyl­silyl-8-amido­quinoline lithium with nickelocene (NiCp(2)). The asymmetric unit contains two symmetry-independent mol­ecules with the Ni atoms in distorted tetra­hedral environments. International Union of Crystallography 2009-12-04 /pmc/articles/PMC2980055/ /pubmed/21579956 http://dx.doi.org/10.1107/S1600536809051708 Text en © Malassa et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Malassa, Astrid
Jäger, Benjamin
Görls, Helmar
Westerhausen, Matthias
Bis(N-triisopropyl­silyl­quinolin-8-aminato)nickel(II)
title Bis(N-triisopropyl­silyl­quinolin-8-aminato)nickel(II)
title_full Bis(N-triisopropyl­silyl­quinolin-8-aminato)nickel(II)
title_fullStr Bis(N-triisopropyl­silyl­quinolin-8-aminato)nickel(II)
title_full_unstemmed Bis(N-triisopropyl­silyl­quinolin-8-aminato)nickel(II)
title_short Bis(N-triisopropyl­silyl­quinolin-8-aminato)nickel(II)
title_sort bis(n-triisopropyl­silyl­quinolin-8-aminato)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980055/
https://www.ncbi.nlm.nih.gov/pubmed/21579956
http://dx.doi.org/10.1107/S1600536809051708
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