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4-Chloro-N-(2-methoxyphenyl)benzamide
The title compound, C(14)H(12)ClNO(2), was prepared by refluxing 4-chlorobenzoyl chloride with o-anisidine in CHCl(3). The methoxyphenyl–amide segment of the molecule is almost planar, with a dihedral angle of 5.10 (7)° between the benzene ring and the C—N—C(O)—C fragment. A weak intramolecular...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980066/ https://www.ncbi.nlm.nih.gov/pubmed/21580098 http://dx.doi.org/10.1107/S160053680905394X |
Sumario: | The title compound, C(14)H(12)ClNO(2), was prepared by refluxing 4-chlorobenzoyl chloride with o-anisidine in CHCl(3). The methoxyphenyl–amide segment of the molecule is almost planar, with a dihedral angle of 5.10 (7)° between the benzene ring and the C—N—C(O)—C fragment. A weak intramolecular N—H⋯O contact forms an S(5) ring and contributes to the planarity of this portion of the molecule. The two benzene rings are inclined at an angle of 26.74 (7)°. In the crystal structure, intermolecular Cl⋯O interactions of 3.1874 (9) Å generate centrosymmetric dimers. These are further linked by C—H⋯O and C—H⋯π interactions, forming inversion related sheets parallel to [001]. |
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