Bis(benzo-15-crown-5-κ(5) O)barium tetrakis­(isothio­cyanato-κN)cobaltate(II)

In the title compound, [Ba(C(14)H(20)O(5))(2)][Co(NCS)(4)], the Ba(II) and Co(II) ions are situated on twofold rotational axes, so asymmetric unit contains half each of the complex cations and anions. The Co(II) ion is coordinated by four N atoms [Co—N 1.83 (2), 1.95 (3) Å] in a distorted tetra­hedr...

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Detalles Bibliográficos
Autores principales: Cao, Zhiqiang, Liu, Kai, Niu, Meiju, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980073/
https://www.ncbi.nlm.nih.gov/pubmed/21579962
http://dx.doi.org/10.1107/S1600536809053471
Descripción
Sumario:In the title compound, [Ba(C(14)H(20)O(5))(2)][Co(NCS)(4)], the Ba(II) and Co(II) ions are situated on twofold rotational axes, so asymmetric unit contains half each of the complex cations and anions. The Co(II) ion is coordinated by four N atoms [Co—N 1.83 (2), 1.95 (3) Å] in a distorted tetra­hedral geometry. The Ba(II) ion is coordinated by ten O atoms [Ba—O 2.766 (19)–2.859 (19) Å] from two benzo-15-crown-5 ligands in a sandwich-like configuration.

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