Bis(benzo-15-crown-5-κ(5) O)barium tetrakis­(isothio­cyanato-κN)cobaltate(II)

In the title compound, [Ba(C(14)H(20)O(5))(2)][Co(NCS)(4)], the Ba(II) and Co(II) ions are situated on twofold rotational axes, so asymmetric unit contains half each of the complex cations and anions. The Co(II) ion is coordinated by four N atoms [Co—N 1.83 (2), 1.95 (3) Å] in a distorted tetra­hedr...

Descripción completa

Detalles Bibliográficos
Autores principales: Cao, Zhiqiang, Liu, Kai, Niu, Meiju, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980073/
https://www.ncbi.nlm.nih.gov/pubmed/21579962
http://dx.doi.org/10.1107/S1600536809053471
_version_ 1782191570912542720
author Cao, Zhiqiang
Liu, Kai
Niu, Meiju
Wang, Daqi
author_facet Cao, Zhiqiang
Liu, Kai
Niu, Meiju
Wang, Daqi
author_sort Cao, Zhiqiang
collection PubMed
description In the title compound, [Ba(C(14)H(20)O(5))(2)][Co(NCS)(4)], the Ba(II) and Co(II) ions are situated on twofold rotational axes, so asymmetric unit contains half each of the complex cations and anions. The Co(II) ion is coordinated by four N atoms [Co—N 1.83 (2), 1.95 (3) Å] in a distorted tetra­hedral geometry. The Ba(II) ion is coordinated by ten O atoms [Ba—O 2.766 (19)–2.859 (19) Å] from two benzo-15-crown-5 ligands in a sandwich-like configuration.
format Text
id pubmed-2980073
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29800732010-12-30 Bis(benzo-15-crown-5-κ(5) O)barium tetrakis­(isothio­cyanato-κN)cobaltate(II) Cao, Zhiqiang Liu, Kai Niu, Meiju Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ba(C(14)H(20)O(5))(2)][Co(NCS)(4)], the Ba(II) and Co(II) ions are situated on twofold rotational axes, so asymmetric unit contains half each of the complex cations and anions. The Co(II) ion is coordinated by four N atoms [Co—N 1.83 (2), 1.95 (3) Å] in a distorted tetra­hedral geometry. The Ba(II) ion is coordinated by ten O atoms [Ba—O 2.766 (19)–2.859 (19) Å] from two benzo-15-crown-5 ligands in a sandwich-like configuration. International Union of Crystallography 2009-12-16 /pmc/articles/PMC2980073/ /pubmed/21579962 http://dx.doi.org/10.1107/S1600536809053471 Text en © Cao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cao, Zhiqiang
Liu, Kai
Niu, Meiju
Wang, Daqi
Bis(benzo-15-crown-5-κ(5) O)barium tetrakis­(isothio­cyanato-κN)cobaltate(II)
title Bis(benzo-15-crown-5-κ(5) O)barium tetrakis­(isothio­cyanato-κN)cobaltate(II)
title_full Bis(benzo-15-crown-5-κ(5) O)barium tetrakis­(isothio­cyanato-κN)cobaltate(II)
title_fullStr Bis(benzo-15-crown-5-κ(5) O)barium tetrakis­(isothio­cyanato-κN)cobaltate(II)
title_full_unstemmed Bis(benzo-15-crown-5-κ(5) O)barium tetrakis­(isothio­cyanato-κN)cobaltate(II)
title_short Bis(benzo-15-crown-5-κ(5) O)barium tetrakis­(isothio­cyanato-κN)cobaltate(II)
title_sort bis(benzo-15-crown-5-κ(5) o)barium tetrakis­(isothio­cyanato-κn)cobaltate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980073/
https://www.ncbi.nlm.nih.gov/pubmed/21579962
http://dx.doi.org/10.1107/S1600536809053471
work_keys_str_mv AT caozhiqiang bisbenzo15crown5k5obariumtetrakisisothiocyanatokncobaltateii
AT liukai bisbenzo15crown5k5obariumtetrakisisothiocyanatokncobaltateii
AT niumeiju bisbenzo15crown5k5obariumtetrakisisothiocyanatokncobaltateii
AT wangdaqi bisbenzo15crown5k5obariumtetrakisisothiocyanatokncobaltateii

Ejemplares similares