{μ-trans-N,N′-Bis[2-(2-hydroxy­ethyl­amino)eth­yl]oxamidato(2−)}bis­[picrato­nickel(II)]

The title complex, [Ni(2)(C(6)H(2)N(3)O(7))(2)(C(10)H(20)N(4)O(4))], contains a centrosymmetric binuclear unit in which the oxamide ligand (located on a centre of symmetry) acts in a bis-­tetra­dentate fashion and the picrate anion binds to nickel(II) in a bidentate mode. The Ni(II) atom displays a...

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Detalles Bibliográficos
Autor principal: Tian, Chunliang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980076/
https://www.ncbi.nlm.nih.gov/pubmed/21579966
http://dx.doi.org/10.1107/S1600536809052933
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author Tian, Chunliang
author_facet Tian, Chunliang
author_sort Tian, Chunliang
collection PubMed
description The title complex, [Ni(2)(C(6)H(2)N(3)O(7))(2)(C(10)H(20)N(4)O(4))], contains a centrosymmetric binuclear unit in which the oxamide ligand (located on a centre of symmetry) acts in a bis-­tetra­dentate fashion and the picrate anion binds to nickel(II) in a bidentate mode. The Ni(II) atom displays a distorted octa­hedral coordination with axial elongation. The binuclear mol­ecules are linked by inter­molecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds into a two-dimensonal supra­molecular network extending parallel to (100).
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spelling pubmed-29800762010-12-30 {μ-trans-N,N′-Bis[2-(2-hydroxy­ethyl­amino)eth­yl]oxamidato(2−)}bis­[picrato­nickel(II)] Tian, Chunliang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ni(2)(C(6)H(2)N(3)O(7))(2)(C(10)H(20)N(4)O(4))], contains a centrosymmetric binuclear unit in which the oxamide ligand (located on a centre of symmetry) acts in a bis-­tetra­dentate fashion and the picrate anion binds to nickel(II) in a bidentate mode. The Ni(II) atom displays a distorted octa­hedral coordination with axial elongation. The binuclear mol­ecules are linked by inter­molecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds into a two-dimensonal supra­molecular network extending parallel to (100). International Union of Crystallography 2009-12-16 /pmc/articles/PMC2980076/ /pubmed/21579966 http://dx.doi.org/10.1107/S1600536809052933 Text en © Tian and Zhou 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tian, Chunliang
{μ-trans-N,N′-Bis[2-(2-hydroxy­ethyl­amino)eth­yl]oxamidato(2−)}bis­[picrato­nickel(II)]
title {μ-trans-N,N′-Bis[2-(2-hydroxy­ethyl­amino)eth­yl]oxamidato(2−)}bis­[picrato­nickel(II)]
title_full {μ-trans-N,N′-Bis[2-(2-hydroxy­ethyl­amino)eth­yl]oxamidato(2−)}bis­[picrato­nickel(II)]
title_fullStr {μ-trans-N,N′-Bis[2-(2-hydroxy­ethyl­amino)eth­yl]oxamidato(2−)}bis­[picrato­nickel(II)]
title_full_unstemmed {μ-trans-N,N′-Bis[2-(2-hydroxy­ethyl­amino)eth­yl]oxamidato(2−)}bis­[picrato­nickel(II)]
title_short {μ-trans-N,N′-Bis[2-(2-hydroxy­ethyl­amino)eth­yl]oxamidato(2−)}bis­[picrato­nickel(II)]
title_sort {μ-trans-n,n′-bis[2-(2-hydroxy­ethyl­amino)eth­yl]oxamidato(2−)}bis­[picrato­nickel(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980076/
https://www.ncbi.nlm.nih.gov/pubmed/21579966
http://dx.doi.org/10.1107/S1600536809052933
work_keys_str_mv AT tianchunliang mtransnnbis22hydroxyethylaminoethyloxamidato2bispicratonickelii

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