(E)-2-Hydr­oxy-6-[(4-propyl­phenyl)­iminiometh­yl]phenolate

The title compound, C(16)H(17)NO(2), crystallizes with three crystallographically independent zwitterionic mol­ecules in the asymmetric unit which differ significantly in the orientations of the propyl side chains. The dihedral angles between the two benzene rings in the three mol­ecules are 6.17 (7...

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Detalles Bibliográficos
Autores principales: Yazıcı, Serap, Albayrak, Çiğdem, Gümrükçüoğlu, İsmail, Şenel, İsmet, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980080/
https://www.ncbi.nlm.nih.gov/pubmed/21580188
http://dx.doi.org/10.1107/S1600536809052246
Descripción
Sumario:The title compound, C(16)H(17)NO(2), crystallizes with three crystallographically independent zwitterionic mol­ecules in the asymmetric unit which differ significantly in the orientations of the propyl side chains. The dihedral angles between the two benzene rings in the three mol­ecules are 6.17 (7), 6.75 (7) and 23.67 (7)°, respectively. In each independent mol­ecule, an intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, each independent mol­ecule exists as part of an O—H⋯O hydrogen-bonded centrosymmetric R (2) (2)(10) dimer.

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