Bis{μ-1-[(2-oxidophen­yl)imino­meth­yl]-2-naphtholato}bis­[pyridine­copper(II)]

The dinuclear title complex, [Cu(2)(C(17)H(11)NO(2))(2)(C(5)H(5)N)(2)], consists of centrosymmetric dimers in which the Cu(II) atom displays an elongated square-pyramidal coordination geometry. The conformation of the dimer is stabilized by inter­molecular C—H⋯O hydrogen bonds and by π–π aromatic st...

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Detalles Bibliográficos
Autores principales: Liu, Kai, Liu, Guihua, Cao, Zhiqiang, Niu, Meiju
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980081/
https://www.ncbi.nlm.nih.gov/pubmed/21579971
http://dx.doi.org/10.1107/S1600536809053665
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author Liu, Kai
Liu, Guihua
Cao, Zhiqiang
Niu, Meiju
author_facet Liu, Kai
Liu, Guihua
Cao, Zhiqiang
Niu, Meiju
author_sort Liu, Kai
collection PubMed
description The dinuclear title complex, [Cu(2)(C(17)H(11)NO(2))(2)(C(5)H(5)N)(2)], consists of centrosymmetric dimers in which the Cu(II) atom displays an elongated square-pyramidal coordination geometry. The conformation of the dimer is stabilized by inter­molecular C—H⋯O hydrogen bonds and by π–π aromatic stacking inter­actions involving the pyridine and benzene rings with centroid–centroid separations of 3.624 (3) Å.
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spelling pubmed-29800812010-12-30 Bis{μ-1-[(2-oxidophen­yl)imino­meth­yl]-2-naphtholato}bis­[pyridine­copper(II)] Liu, Kai Liu, Guihua Cao, Zhiqiang Niu, Meiju Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title complex, [Cu(2)(C(17)H(11)NO(2))(2)(C(5)H(5)N)(2)], consists of centrosymmetric dimers in which the Cu(II) atom displays an elongated square-pyramidal coordination geometry. The conformation of the dimer is stabilized by inter­molecular C—H⋯O hydrogen bonds and by π–π aromatic stacking inter­actions involving the pyridine and benzene rings with centroid–centroid separations of 3.624 (3) Å. International Union of Crystallography 2009-12-19 /pmc/articles/PMC2980081/ /pubmed/21579971 http://dx.doi.org/10.1107/S1600536809053665 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Kai
Liu, Guihua
Cao, Zhiqiang
Niu, Meiju
Bis{μ-1-[(2-oxidophen­yl)imino­meth­yl]-2-naphtholato}bis­[pyridine­copper(II)]
title Bis{μ-1-[(2-oxidophen­yl)imino­meth­yl]-2-naphtholato}bis­[pyridine­copper(II)]
title_full Bis{μ-1-[(2-oxidophen­yl)imino­meth­yl]-2-naphtholato}bis­[pyridine­copper(II)]
title_fullStr Bis{μ-1-[(2-oxidophen­yl)imino­meth­yl]-2-naphtholato}bis­[pyridine­copper(II)]
title_full_unstemmed Bis{μ-1-[(2-oxidophen­yl)imino­meth­yl]-2-naphtholato}bis­[pyridine­copper(II)]
title_short Bis{μ-1-[(2-oxidophen­yl)imino­meth­yl]-2-naphtholato}bis­[pyridine­copper(II)]
title_sort bis{μ-1-[(2-oxidophen­yl)imino­meth­yl]-2-naphtholato}bis­[pyridine­copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980081/
https://www.ncbi.nlm.nih.gov/pubmed/21579971
http://dx.doi.org/10.1107/S1600536809053665
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AT niumeiju bism12oxidophenyliminomethyl2naphtholatobispyridinecopperii

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