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catena-Poly[[[triaquacadmium(II)]-μ-2,2′-[oxalylbis(azanediyl)]diacetato-κ(2) O,O′] dihydrate]
The structure of the polymeric title complex, {[Cd(C(6)H(6)N(2)O(6))(H(2)O)(3)]·2H(2)O}(n), consists of chains running parallel to [[Image: see text]01] in which the oxamidato ligand, deprotonated only at the carboxylate groups, acts as a bridging bis-monodentate ligand. The Cd atom and the O atom...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980082/ https://www.ncbi.nlm.nih.gov/pubmed/21579934 http://dx.doi.org/10.1107/S1600536809052015 |
Sumario: | The structure of the polymeric title complex, {[Cd(C(6)H(6)N(2)O(6))(H(2)O)(3)]·2H(2)O}(n), consists of chains running parallel to [[Image: see text]01] in which the oxamidato ligand, deprotonated only at the carboxylate groups, acts as a bridging bis-monodentate ligand. The Cd atom and the O atom of a coordinated water molecule are located on a twofold axis. The coordination geometry around the Cd atom is distorted trigonal-pyramidal. In the crystal structure, neighbouring chains are linked into a three-dimensional network by interchain O—H⋯O and N—H⋯O hydrogen bonds. |
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