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N,N′-Bis(phenylsulfonyl)succinamide
In the crystal structure of the title compound, C(16)H(16)N(2)O(6)S(2), the conformation of the N—C bonds in the C—SO(2)—NH—C(O)—C segments have gauche torsions with respect to the S=O bonds, while the conformations of the N—H and C=O bonds in the amide fragments are trans to each other and the amid...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980084/ https://www.ncbi.nlm.nih.gov/pubmed/21580066 http://dx.doi.org/10.1107/S1600536809053537 |
Sumario: | In the crystal structure of the title compound, C(16)H(16)N(2)O(6)S(2), the conformation of the N—C bonds in the C—SO(2)—NH—C(O)—C segments have gauche torsions with respect to the S=O bonds, while the conformations of the N—H and C=O bonds in the amide fragments are trans to each other and the amide O atom is anti to the H atoms attached to the adjacent C atom. The molecule is bent at the S atom with a C—SO(2)—NH—C(O) torsion angle of 65.2 (2)°. The molecule lies about a centre of inversion. The dihedral angle between the benzene ring and the SO(2)—NH—C(O)—C(2) segment in the two halves of the molecule is 77.4 (1)°. The structure exhibits both intramolecular and intermolecular hydrogen bonds. A series of N—H⋯O(S) hydrogen bonds links the molecules into infinite chains. |
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