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N,N′-Bis(phenyl­sulfon­yl)succinamide

In the crystal structure of the title compound, C(16)H(16)N(2)O(6)S(2), the conformation of the N—C bonds in the C—SO(2)—NH—C(O)—C segments have gauche torsions with respect to the S=O bonds, while the conformations of the N—H and C=O bonds in the amide fragments are trans to each other and the amid...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Suchetan, P. A., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980084/
https://www.ncbi.nlm.nih.gov/pubmed/21580066
http://dx.doi.org/10.1107/S1600536809053537
Descripción
Sumario:In the crystal structure of the title compound, C(16)H(16)N(2)O(6)S(2), the conformation of the N—C bonds in the C—SO(2)—NH—C(O)—C segments have gauche torsions with respect to the S=O bonds, while the conformations of the N—H and C=O bonds in the amide fragments are trans to each other and the amide O atom is anti to the H atoms attached to the adjacent C atom. The mol­ecule is bent at the S atom with a C—SO(2)—NH—C(O) torsion angle of 65.2 (2)°. The molecule lies about a centre of inversion. The dihedral angle between the benzene ring and the SO(2)—NH—C(O)—C(2) segment in the two halves of the mol­ecule is 77.4 (1)°. The structure exhibits both intra­molecular and inter­molecular hydrogen bonds. A series of N—H⋯O(S) hydrogen bonds links the mol­ecules into infinite chains.