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N,N′-Bis(phenyl­sulfon­yl)succinamide

In the crystal structure of the title compound, C(16)H(16)N(2)O(6)S(2), the conformation of the N—C bonds in the C—SO(2)—NH—C(O)—C segments have gauche torsions with respect to the S=O bonds, while the conformations of the N—H and C=O bonds in the amide fragments are trans to each other and the amid...

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Autores principales: Gowda, B. Thimme, Foro, Sabine, Suchetan, P. A., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980084/
https://www.ncbi.nlm.nih.gov/pubmed/21580066
http://dx.doi.org/10.1107/S1600536809053537
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author Gowda, B. Thimme
Foro, Sabine
Suchetan, P. A.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Suchetan, P. A.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description In the crystal structure of the title compound, C(16)H(16)N(2)O(6)S(2), the conformation of the N—C bonds in the C—SO(2)—NH—C(O)—C segments have gauche torsions with respect to the S=O bonds, while the conformations of the N—H and C=O bonds in the amide fragments are trans to each other and the amide O atom is anti to the H atoms attached to the adjacent C atom. The mol­ecule is bent at the S atom with a C—SO(2)—NH—C(O) torsion angle of 65.2 (2)°. The molecule lies about a centre of inversion. The dihedral angle between the benzene ring and the SO(2)—NH—C(O)—C(2) segment in the two halves of the mol­ecule is 77.4 (1)°. The structure exhibits both intra­molecular and inter­molecular hydrogen bonds. A series of N—H⋯O(S) hydrogen bonds links the mol­ecules into infinite chains.
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spelling pubmed-29800842010-12-30 N,N′-Bis(phenyl­sulfon­yl)succinamide Gowda, B. Thimme Foro, Sabine Suchetan, P. A. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(16)H(16)N(2)O(6)S(2), the conformation of the N—C bonds in the C—SO(2)—NH—C(O)—C segments have gauche torsions with respect to the S=O bonds, while the conformations of the N—H and C=O bonds in the amide fragments are trans to each other and the amide O atom is anti to the H atoms attached to the adjacent C atom. The mol­ecule is bent at the S atom with a C—SO(2)—NH—C(O) torsion angle of 65.2 (2)°. The molecule lies about a centre of inversion. The dihedral angle between the benzene ring and the SO(2)—NH—C(O)—C(2) segment in the two halves of the mol­ecule is 77.4 (1)°. The structure exhibits both intra­molecular and inter­molecular hydrogen bonds. A series of N—H⋯O(S) hydrogen bonds links the mol­ecules into infinite chains. International Union of Crystallography 2009-12-16 /pmc/articles/PMC2980084/ /pubmed/21580066 http://dx.doi.org/10.1107/S1600536809053537 Text en © Gowda et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Suchetan, P. A.
Fuess, Hartmut
N,N′-Bis(phenyl­sulfon­yl)succinamide
title N,N′-Bis(phenyl­sulfon­yl)succinamide
title_full N,N′-Bis(phenyl­sulfon­yl)succinamide
title_fullStr N,N′-Bis(phenyl­sulfon­yl)succinamide
title_full_unstemmed N,N′-Bis(phenyl­sulfon­yl)succinamide
title_short N,N′-Bis(phenyl­sulfon­yl)succinamide
title_sort n,n′-bis(phenyl­sulfon­yl)succinamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980084/
https://www.ncbi.nlm.nih.gov/pubmed/21580066
http://dx.doi.org/10.1107/S1600536809053537
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