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N,N′-Bis(phenylsulfonyl)succinamide
In the crystal structure of the title compound, C(16)H(16)N(2)O(6)S(2), the conformation of the N—C bonds in the C—SO(2)—NH—C(O)—C segments have gauche torsions with respect to the S=O bonds, while the conformations of the N—H and C=O bonds in the amide fragments are trans to each other and the amid...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980084/ https://www.ncbi.nlm.nih.gov/pubmed/21580066 http://dx.doi.org/10.1107/S1600536809053537 |
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author | Gowda, B. Thimme Foro, Sabine Suchetan, P. A. Fuess, Hartmut |
author_facet | Gowda, B. Thimme Foro, Sabine Suchetan, P. A. Fuess, Hartmut |
author_sort | Gowda, B. Thimme |
collection | PubMed |
description | In the crystal structure of the title compound, C(16)H(16)N(2)O(6)S(2), the conformation of the N—C bonds in the C—SO(2)—NH—C(O)—C segments have gauche torsions with respect to the S=O bonds, while the conformations of the N—H and C=O bonds in the amide fragments are trans to each other and the amide O atom is anti to the H atoms attached to the adjacent C atom. The molecule is bent at the S atom with a C—SO(2)—NH—C(O) torsion angle of 65.2 (2)°. The molecule lies about a centre of inversion. The dihedral angle between the benzene ring and the SO(2)—NH—C(O)—C(2) segment in the two halves of the molecule is 77.4 (1)°. The structure exhibits both intramolecular and intermolecular hydrogen bonds. A series of N—H⋯O(S) hydrogen bonds links the molecules into infinite chains. |
format | Text |
id | pubmed-2980084 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29800842010-12-30 N,N′-Bis(phenylsulfonyl)succinamide Gowda, B. Thimme Foro, Sabine Suchetan, P. A. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(16)H(16)N(2)O(6)S(2), the conformation of the N—C bonds in the C—SO(2)—NH—C(O)—C segments have gauche torsions with respect to the S=O bonds, while the conformations of the N—H and C=O bonds in the amide fragments are trans to each other and the amide O atom is anti to the H atoms attached to the adjacent C atom. The molecule is bent at the S atom with a C—SO(2)—NH—C(O) torsion angle of 65.2 (2)°. The molecule lies about a centre of inversion. The dihedral angle between the benzene ring and the SO(2)—NH—C(O)—C(2) segment in the two halves of the molecule is 77.4 (1)°. The structure exhibits both intramolecular and intermolecular hydrogen bonds. A series of N—H⋯O(S) hydrogen bonds links the molecules into infinite chains. International Union of Crystallography 2009-12-16 /pmc/articles/PMC2980084/ /pubmed/21580066 http://dx.doi.org/10.1107/S1600536809053537 Text en © Gowda et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gowda, B. Thimme Foro, Sabine Suchetan, P. A. Fuess, Hartmut N,N′-Bis(phenylsulfonyl)succinamide |
title |
N,N′-Bis(phenylsulfonyl)succinamide |
title_full |
N,N′-Bis(phenylsulfonyl)succinamide |
title_fullStr |
N,N′-Bis(phenylsulfonyl)succinamide |
title_full_unstemmed |
N,N′-Bis(phenylsulfonyl)succinamide |
title_short |
N,N′-Bis(phenylsulfonyl)succinamide |
title_sort | n,n′-bis(phenylsulfonyl)succinamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980084/ https://www.ncbi.nlm.nih.gov/pubmed/21580066 http://dx.doi.org/10.1107/S1600536809053537 |
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