Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) penta­hydrate

In the title compound, [Ni(C(2)H(8)N(2))(3)](2)[Mo(CN)(8)]·5H(2)O, the Ni(II) ion is coordinated by six N atoms from three ethane-1,2-diamine ligands in a distorted octa­hedral geometry, while the Mo(IV) atom is coordianted by eight cyanide ligands. The Ni—N bond distances range from 2.1061 (18) to...

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Detalles Bibliográficos
Autores principales: Jun, Qian, Zhang, Chi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980088/
https://www.ncbi.nlm.nih.gov/pubmed/21579925
http://dx.doi.org/10.1107/S1600536809051964
Descripción
Sumario:In the title compound, [Ni(C(2)H(8)N(2))(3)](2)[Mo(CN)(8)]·5H(2)O, the Ni(II) ion is coordinated by six N atoms from three ethane-1,2-diamine ligands in a distorted octa­hedral geometry, while the Mo(IV) atom is coordianted by eight cyanide ligands. The Ni—N bond distances range from 2.1061 (18) to 2.1425 (18) Å. The Mo—C and C—N distances in the [Mo(CN)(8)] unit range from 2.154 (2) to 2.174 (2) Å and 1.149 (3) to 1.156 (3) Å, respectively. The complex ions and water mol­ecules are linked by weak N—H⋯N/O and O—H⋯N/O hydrogen bonds into a three-demensional structure.

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